Ether-and alcohol-functionalized task-specific ionic liquids: attractive properties and applications

S Tang, GA Baker, H Zhao - Chemical Society Reviews, 2012 - pubs.rsc.org
In recent years, the designer nature of ionic liquids (ILs) has driven their exploration and
exploitation in countless fields among the physical and chemical sciences. A fair measure of …

Protein stabilization and enzyme activation in ionic liquids: specific ion effects

H Zhao - Journal of Chemical Technology & Biotechnology, 2016 - Wiley Online Library
There are still debates on whether the hydration of ions perturbs the water structure, and
what is the degree of such disturbance; therefore, the origin of the Hofmeister effect on …

Recent advances of enzymatic reactions in ionic liquids

M Moniruzzaman, K Nakashima, N Kamiya… - Biochemical Engineering …, 2010 - Elsevier
The tremendous potential of room temperature ionic liquids as an alternative to
environmentally harmful ordinary organic solvents is well recognized. Ionic liquids, having …

Methods for stabilizing and activating enzymes in ionic liquids—a review

H Zhao - Journal of Chemical Technology & Biotechnology, 2010 - Wiley Online Library
Ionic liquids (ILs) have evolved as a new type of non‐aqueous solvents for biocatalysis,
mainly due to their unique and tunable physical properties. A number of recent review …

Biocatalysis and biomass conversion in alternative reaction media

RA Sheldon - Chemistry–A European Journal, 2016 - Wiley Online Library
In this Minireview, the state of the art in the use of ionic liquids (ILs) and deep eutectic
solvents (DESs) as alternative reaction media for biocatalytic processes and biomass …

Activation and stabilization of enzymes in ionic liquids

M Moniruzzaman, N Kamiya, M Goto - Organic & biomolecular …, 2010 - pubs.rsc.org
As environmentally benign “green” solvents, room temperature ionic liquids (ILs) have been
used as solvents or (co) solvents in biocatalytic reactions and processes for a decade. The …

Biocatalysis in ionic liquids: state-of-the-union

RA Sheldon - Green Chemistry, 2021 - pubs.rsc.org
This perspective reviews the current status and prospects of biocatalysis in ionic liquids.
Although they are not strictly speaking ionic liquids, deep eutectic solvents are included …

“Nonsolvent” applications of ionic liquids in biotransformations and organocatalysis

P Domínguez de María - Angewandte Chemie International …, 2008 - Wiley Online Library
The application of room‐temperature ionic liquids (RTILs) as (co) solvents and/or reagents is
well documented. However, RTILS also have “nonsolvent” applications in …

What do we learn from enzyme behaviors in organic solvents?–Structural functionalization of ionic liquids for enzyme activation and stabilization

H Zhao - Biotechnology Advances, 2020 - Elsevier
Enzyme activity in nonaqueous media (eg conventional organic solvents) is typically lower
than in water by several orders of magnitude. There is a rising interest of developing new …

Key factors affecting the activity and stability of enzymes in ionic liquids and novel applications in biocatalysis

WW Gao, FX Zhang, GX Zhang, CH Zhou - Biochemical engineering …, 2015 - Elsevier
Ionic liquids as eco-friendly solvent media and catalyst play very important roles in many
enzymatic reactions such as enzymatic biotransformation and all kinds of biosynthesis due …