The development of synthetic methods for the introduction of the fluorine atom and
fluoroalklyl groups into organic molecules has gained increased attention. Synthetic organic …

Synthetic chemistry plays an indispensable role in drug discovery, contributing to hit
compounds identification, lead compounds optimization, candidate drugs preparation, and …

The formation of highly enantioenriched boronic esters through both stoichiometric and
catalytic methods has received much attention over the past decade. Accordingly, the …

A method for deoxyfluorination of aliphatic primary, secondary, and tertiary alcohols is
reported, employing a nontrigonal phosphorus triamide for base-free alcohol activation in …

Copper-catalyzed stereospecific cross-couplings of boronic esters are reported. Boron “ate”
complexes derived from pinacol boronic esters and tert-butyl lithium undergo stereospecific …

This review discusses recent advances in the chemistry of saturated boronic acids,
boronates, and trifluoroborates. Applications of the title compounds in the design of boron …

Aryl fluorides are important structural motifs in many pharmaceuticals. Although the Balz–
Schiemann reaction provides an entry to aryl fluorides from aryldiazonium …

The stereospecific cross-coupling of secondary boronic esters with sp2 electrophiles (Suzuki–
Miyaura reaction) is a long-standing problem in synthesis, but progress has been achieved …

We report a two-step strategy for diverse hydrofunctionalizations of aliphatic internal alkenes
with high regioselectivity and enantioselectivity. This process comprises a copper-catalyzed …

Monofluorinated alkyl compounds are of great importance in pharmaceuticals,
agrochemicals and materials. Herein, we describe a direct nickel‐catalyzed …