Single-atom alloy catalysis
RT Hannagan, G Giannakakis… - Chemical …, 2020 - ACS Publications
Single-atom alloys (SAAs) play an increasingly significant role in the field of single-site
catalysis and are typically composed of catalytically active elements atomically dispersed in …
catalysis and are typically composed of catalytically active elements atomically dispersed in …
Single-atom alloys as a reductionist approach to the rational design of heterogeneous catalysts
G Giannakakis… - Accounts of chemical …, 2018 - ACS Publications
Conspectus Heterogeneous catalysts are workhorses in the industrial production of most
commodity and specialty chemicals, and have widespread energy and environmental …
commodity and specialty chemicals, and have widespread energy and environmental …
Electrochemical CO2 Reduction over Compressively Strained CuAg Surface Alloys with Enhanced Multi-Carbon Oxygenate Selectivity
The electrochemical reduction of carbon dioxide using renewably generated electricity offers
a potential means for producing fuels and chemicals in a sustainable manner. To date …
a potential means for producing fuels and chemicals in a sustainable manner. To date …
Importance of Ag–Cu Biphasic Boundaries for Selective Electrochemical Reduction of CO2 to Ethanol
In recent years, electrochemical reduction of carbon dioxide (CO2) has received a great deal
of attention due to the potential that this process can mitigate the atmospheric CO2 …
of attention due to the potential that this process can mitigate the atmospheric CO2 …
Regulating and identifying the structures of PdAu alloys with splendid oxygen reduction activity for rechargeable zinc–air batteries
Alloying improves catalytic performance, but the control is challenging due to element
contributions. Here, we study the structural differences in PdxAuy alloys to understand their …
contributions. Here, we study the structural differences in PdxAuy alloys to understand their …
[HTML][HTML] Selective hydrogenation of 1, 3-butadiene on platinum–copper alloys at the single-atom limit
Platinum is ubiquitous in the production sectors of chemicals and fuels; however, its scarcity
in nature and high price will limit future proliferation of platinum-catalysed reactions. One …
in nature and high price will limit future proliferation of platinum-catalysed reactions. One …
Lonely atoms with special gifts: breaking linear scaling relationships in heterogeneous catalysis with single-atom alloys
We discuss a simple yet effective strategy for escaping traditional linear scaling relations in
heterogeneous catalysis with highly dilute bimetallic alloys known as single-atom alloys …
heterogeneous catalysis with highly dilute bimetallic alloys known as single-atom alloys …
Grain boundary complexions
Grain boundaries exhibit phase-like behavior in which their structure, chemistry and
properties may change discontinuously at critical values of thermodynamic parameters such …
properties may change discontinuously at critical values of thermodynamic parameters such …
Review of Pt-based bimetallic catalysis: from model surfaces to supported catalysts
The field of heterogeneous catalysis, specifically catalysis on bimetallic alloys, has seen
many advances over the past few decades. Bimetallic catalysts, which often show electronic …
many advances over the past few decades. Bimetallic catalysts, which often show electronic …
Theoretical heterogeneous catalysis: scaling relationships and computational catalyst design
J Greeley - Annual review of chemical and biomolecular …, 2016 - annualreviews.org
Scaling relationships are theoretical constructs that relate the binding energies of a wide
variety of catalytic intermediates across a range of catalyst surfaces. Such relationships are …
variety of catalytic intermediates across a range of catalyst surfaces. Such relationships are …