Cluster complexes have attracted interest for decades due to their promise of drawing
analogies to metallic surfaces and metalloenzyme active sites, but only recently have …

Nitrene‐transfer reactions are powerful synthetic tools for the direct incorporation of nitrogen
atoms into organic molecules. The discovery of novel nitrene‐transfer reactions has been …

The field of multimetallic catalysis is rapidly developing and some multimetallic complexes
catalyze organic transformations to yield the desired products in more efficient ways owing …

Intelligent molecular machines that are driven by light, electricity, and temperature have
attracted considerable interest in the fields of chemistry, materials, and biology. Herein, a …

Tetra-ortho-fluoro-azobenzenes are a class of photoswitches useful for the construction of
visible-light-controlled molecular systems. They can be used to achieve spatio-temporal …

Simple and efficient methods are a key consideration for small molecule and polymer
syntheses. Direct arylation polymerization (DArP) is of increasing interest for preparing …

Photoswitchable catalysts are becoming attractive materials for catalytic applications
because of their favorable characteristics, such as customizable catalytic activity and …

Conspectus Bimetallic motifs are a structural feature common to some of the most effective
and synthetically useful catalysts known, including in the active sites of many …

Cooperatively bimetallic organic catalysis, coupling actions of two metal centers in a
catalytic organic transformation via co‐activation of a single molecule or synergistic …

A naphthyridine‐derived expanded pincer ligand is described that can host two copper (I)
centers. The proton‐responsive ligand can undergo reversible partial and full …