Regioselective preparation of saturated spirocyclic and ring-expanded fused pyrazoles

RR Merchant, DM Allwood… - The Journal of Organic …, 2014 - ACS Publications
Saturated bicyclic pyrazoles represent an important class of biologically active molecules,
but their preparation can be hampered by labor-intensive synthesis of required starting …

Recent developments in the chemistry of Negishi coupling: a review

Muzammil, AF Zahoor, B Parveen, S Javed, R Akhtar… - Chemical Papers, 2024 - Springer
Negishi cross-coupling reaction is a familiar reaction for the formation of carbon–carbon
bonds that couples organic halides or triflates with organozinc compounds. Palladium is …

Fluorenone Schiff base derivative complexes of ruthenium, rhodium and iridium exhibiting efficient antibacterial activity and DNA-binding affinity

MR Kollipara, L Shadap, V Banothu, N Agarwal… - Journal of …, 2020 - Elsevier
Abstract Metal precursors [(arene) MCl 2] 2 (arene= p-cymene, Cp∗; M= Ru, Rh and Ir) on
reacting with 9-fluorenone derivative ligands L1, L2 and L3 resulted in the formation of …

3-Alkyl-1, 2-cyclopentanediones by Negishi cross-coupling of a 3-bromo-1, 2-cyclopentanedione silyl enol ether with alkylzinc reagents: An approach to 2-substituted …

A Paju, D Kostomarova, K Matkevitš, M Laos, T Pehk… - Tetrahedron, 2015 - Elsevier
Negishi cross-coupling of the silyl-protected 3-bromoenol of 1, 2-cyclopentanedione with
primary and secondary alkylzinc reagents using Pd-catalysts affords 3-alkyl substituted 1, 2 …

Photochromism of tetrahydroindolizines. Part XIV: synthesis of cis-fixed conjugated photochromic pyridazinopyrrolo [1, 2-b] isoquinolines incorporating carbon-rich …

SA Ahmed, KS Khairou, BH Asghar, HA Muathen… - Tetrahedron …, 2014 - Elsevier
New carbon-rich photochromic tetrahydroindolizines (THIs) bearing dihydroisoquinoline
derivatives as heterocyclic bases (region B) have been synthesized via different chemical …

Photochromism of dihydroindolizines. Part XXI: multiaddressable photochromic performances based on pyrrolo [1, 2-b] pyridazine photochromes: kinetics, substituent …

N El Guesmi, SA Ahmed, II Althagafi… - Journal of Photochemistry …, 2017 - Elsevier
In the present study, the thermal 1, 5-electrocyclization back reaction from betaines (colored
forms) to dihydroindolizines (DHIs, colorless) was studied in seven organic solvents with …

[PDF][PDF] Fluorenone hydrazone derivatives as efficient inhibitors of acidic and pitting corrosion of carbon steel

B Jahdaly, II Althagafi, M Abdallah… - Journal of Materials …, 2016 - researchgate.net
The inhibiting effect of some fluorenone hydrazone derivatives toward the corrosion of
carbon steel in 1.0 MH2SO4 solution was studied using galvanostatic polarization and …

Photochromism of dihydroindolizines. Part XXII: Significant effect of region B substituents on tuning the photophysical properties of photochromic dihydroindolizines …

N El Guesmi, SA Ahmed, F Maurel, II Althagafi… - … of Photochemistry and …, 2017 - Elsevier
Novel photochromic dihydroindolizines (DHIs) bearing different alkyl and cyclic alkyl ester
group (region B) were prepared via electrophilic addition of fluorene spirocyclopropenes …

Photochromism of dihydroindolizines Part XIX. Efficient one‐pot solid‐state synthesis, kinetic, and computational studies based on dihydroindolizine photochromes

SA Ahmed, N El Guesmi, BH Asghar… - Journal of Physical …, 2017 - Wiley Online Library
For the first time, one‐pot solid‐state synthesis of 12 photochromic materials based on
photochromic dihydroindolizine system substituted in both fluorene part (region A) and the …

Photochromism of tetrahydroindolizines. Part XXV: Mechanochemical synthesis, distinctive photophysical tuning and computational studies of novel …

N El Guesmi, HM Altass, F Maurel, RJ Obaid… - … of Photochemistry and …, 2021 - Elsevier
A new mechanochemical synthetic strategy for the synthesis of novel tetrahydroindolizines
(THIs) photochromes incorporating different substituents in both regions B (ester part), and …