The extraordinary reactivity exhibited by many Fe–S enzymes is due in large part to the influence of the protein scaffold on substrate binding and activation. In principle, the …
Abstract 1 H NMR and EPR techniques were used to investigate the electron spin distribution and electronic ground state in several iron tetrapyrrolic macrocycles. The first …
The synthesis, structure, spectroscopy, electrochemistry, and reactivity of the novel oxo complexes Pr $\sb4 $ N (Ru $\sp {\rm V} $(O) PHAB), Pr $\sb4 $ N (Ru $\sp {\rm V} $(O) bp …
The coordination chemistry of carboxamido nitrogen bound to Fe III has opened the door to a new area of iron chemistry. Following the discovery of this type of coordination in nature …