An important strategy for the efficient generation of diversity in molecular structures is the
utilization of common starting materials in chemodivergent transformations. The most …

The development of switchable chemo-, regio-, or diastereodivergent reactions, in which two
or more structurally and stereogenically different types of chiral products could be produced …

A remaining challenge in the synthetic chemistry field is formation of all-carbon quaternary
centers, a feature found in many natural products, particularly in spirocycle systems. 1 …

The principle of vinylogy states that the electronic effects of a functional group in a molecule
are possibly transmitted to a distal position through interposed conjugated multiple bonds …

Cycloaddition reactions are among the most important tools for the construction of cyclic
compounds in organic synthesis, since these reactions are vital to access natural products …

We report herein a gold and palladium sequential catalysis system to access furan‐fused
nine‐membered heterocycles in high efficiency and enantioselectivity. In this one‐pot …

Regulating both the chemo‐and diastereoselectivity, divergently, of a reaction is highly
attractive but extremely challenging. Presented herein is a catalyst‐controlled switch in the …

A highly diastereo-and enantioselective methodology for the asymmetric synthesis of vicinal
diaxial styrenes and multiaxis system was achieved by organocatalysis. Various vicinal …

The reactive oxygen species (ROS) including hypochlorous acid (HOCl), on the one hand
they can regulate physiological function in our living organisms, on the other hand abnormal …

Building small-molecule libraries with structural and stereogenic diversity plays an important
role in drug discovery. The development of switchable intermolecular cycloaddition …