Two-Dimensional Negative Thermal Expansion in a Crystal of LiBO2

X Zhang, X Jiang, MS Molokeev, N Wang… - Chemistry of …, 2022 - ACS Publications
Negative thermal expansion (NTE), violating the common sense of “thermal expansion and
cold contraction” effects, is a novel temperature-responding behavior of great scientific and …

[HTML][HTML] Molecular imine cages with π-basic Au 3 (pyrazolate) faces

N Eren, F Fadaei-Tirani, R Scopelliti, K Severin - Chemical Science, 2024 - pubs.rsc.org
One tetrahedral and two trigonal prismatic cages with π-basic Au3 (pyrazolate) 3 faces were
obtained by connection of pre-formed gold complexes via dynamic covalent imine chemistry …

The π-acidic coinage-metal cyclic trinuclear complexes with Lewis or π-bases and the relevant applications

GQ Huang, X Chen, J Zheng, D Li - Journal of Organometallic Chemistry, 2023 - Elsevier
Coinage-metal cyclic trinuclear complexes (CTCs) with azolate ligand equipped with strong
electron-withdrawing substituents (eg, CF 3, NO 2) represent the underlying members in the …

[HTML][HTML] Aggregation-induced phosphorescence sensitization in two heptanuclear and decanuclear gold–silver sandwich clusters

Z Lu, YJ Yang, WX Ni, M Li, Y Zhao, YL Huang… - Chemical …, 2021 - pubs.rsc.org
The strategy of aggregation-induced emission enhancement (AIEE) has been proven to be
efficient in wide areas and has recently been adopted in the field of metal nanoclusters …

Efficient adsorptive removal of dibenzothiophenes from liquid fuel over a novel triangular Ag (I) complex

X Feng, L Qu, X Chen, L Yang, Y Zhang, Y Wang… - Separation and …, 2022 - Elsevier
The use of a π-acidic triangular silver (I) pyrazolate (Ag 3 pz 3) as an adsorbent for
adsorptive desulfurization (ADS) has been investigated in this report. Ag 3 pz 3 shows very …

Modulating the extent of anisotropic cuprophilicity via high pressure with piezochromic luminescence sensitization

Z Lu, CM Archambault, S Li, U Syed… - The Journal of …, 2023 - ACS Publications
Metallophilicity has been widely studied as a fundamental supramolecular interaction.
However, the extent and directionality thereof remain controversial. A major obstacle lies in …

Adducts of a Triangular Copper (I) Pyrazolate with Thiophenic Compounds Featuring Short Cu (I)–S Contacts

L Qu, X Feng, L Ma, Y Wang, SW Ng… - Crystal Growth & …, 2023 - ACS Publications
The acidic triangular copper (I) 4-nitro-3, 5-bis (trifluoromethyl) pyrazolate (Cu 3 pz 3) and its
adducts with thiophenic compounds were prepared and structurally characterized by X-ray …

Luminescence Screening of Copper and Gold Mixed Ligand Complexes with S-/P-Donor Atoms: An Advanced Multiweek Research Discovery Experiment for the …

K Bodenstedt, JL Fripp, S Li, Z Lu… - Journal of Chemical …, 2022 - ACS Publications
An advanced research discovery laboratory course in inorganic chemistry has been
developed to engage undergraduate students in authentic research experiences directly …

A Broadened Class of Donor‐Acceptor Stacked Macrometallacyclic Adducts of Different Coinage Metals

Z Lu, L Luciani, S Li, VN Nesterov… - … A European Journal, 2024 - Wiley Online Library
A yet‐outstanding supramolecular chemistry challenge is isolation of novel varieties of
stacked complexes with fine‐tuned donor‐acceptor bonding and optoelectronic properties …

Relativistic modulation of supramolecular halogen/copper interactions and phosphorescence in Cu (i) pyrazolate cyclotrimers

Z Lu, M Vanga, S Li, JO Adebanjo, MR Patterson… - Dalton …, 2023 - pubs.rsc.org
Described herein are the synthesis, structure, and photophysics of the iodo-substituted cyclic
trinuclear copper (I) complex, Cu3 [4-I-3, 5-(CF3) 2Pz] 3 supported by a highly-fluorinated …