The Scholl reaction as a powerful tool for synthesis of curved polycyclic aromatics

Y Zhang, SH Pun, Q Miao - Chemical Reviews, 2022 - ACS Publications
The past decade has witnessed remarkable success in the synthesis of curved polycyclic
aromatics through Scholl reactions which enable oxidative aryl–aryl coupling even in …

Nanographenes and graphene nanoribbons as multitalents of present and future materials science

Y Gu, Z Qiu, K Müllen - Journal of the American Chemical …, 2022 - ACS Publications
As cut-outs from a graphene sheet, nanographenes (NGs) and graphene nanoribbons
(GNRs) are ideal cases with which to connect the world of molecules with that of bulk carbon …

Transition-metal-catalyzed silylation and borylation of C–H bonds for the synthesis and functionalization of complex molecules

IF Yu, JW Wilson, JF Hartwig - Chemical Reviews, 2023 - ACS Publications
The functionalization of C–H bonds in organic molecules containing functional groups has
been one of the holy grails of catalysis. One synthetically important approach to the diverse …

Structurally constrained boron-, nitrogen-, silicon-, and phosphorus-centered polycyclic π-conjugated systems

M Hirai, N Tanaka, M Sakai, S Yamaguchi - Chemical reviews, 2019 - ACS Publications
Incorporation of main group elements into the π-conjugated frameworks is a sophisticated
strategy to alter the fundamental nature of the parent conjugated π-systems, giving rise to …

Small size, big impact: recent progress in bottom‐up synthesized nanographenes for optoelectronic and energy applications

Z Liu, S Fu, X Liu, A Narita, P Samorì, M Bonn… - Advanced …, 2022 - Wiley Online Library
Bottom‐up synthesized graphene nanostructures, including 0D graphene quantum dots and
1D graphene nanoribbons, have recently emerged as promising candidates for efficient …

Synthetic applications of oxidative aromatic coupling—from biphenols to nanographenes

M Grzybowski, B Sadowski… - Angewandte Chemie …, 2020 - Wiley Online Library
Oxidative aromatic coupling occupies a fundamental place in the modern chemistry of
aromatic compounds. It is a method of choice for the assembly of large and bewildering …

Polycyclic arene synthesis by annulative π-extension

H Ito, Y Segawa, K Murakami… - Journal of the American …, 2018 - ACS Publications
Annulative π-extension (APEX) has emerged as a powerful and efficient synthetic method
for the construction of polycyclic aromatic hydrocarbons, nanographenes, and π-extended …

Construction of heptagon‐containing molecular nanocarbons

Chaolumen, IA Stepek, KE Yamada… - Angewandte Chemie …, 2021 - Wiley Online Library
Molecular nanocarbons containing heptagonal rings have attracted increasing interest due
to their dynamic behavior, electronic properties, aromaticity, and solid‐state packing …

A Nanographene‐Based Two‐Dimensional Covalent Organic Framework as a Stable and Efficient Photocatalyst

E Jin, S Fu, H Hanayama, MA Addicoat… - Angewandte Chemie …, 2022 - Wiley Online Library
Synthesis of covalent organic frameworks (COFs) with desirable organic units furnishes
advanced materials with unique functionalities. As an emerging class of two‐dimensional …

Recent advances in C–H activation for the synthesis of π-extended materials

IA Stepek, K Itami - ACS Materials Letters, 2020 - ACS Publications
The activation of typically unreactive aromatic C–H bonds by transition-metal catalysis has
been receiving increased attention from the synthetic chemistry community in recent years …