Abstract The stereospecific 1, 2‐migration of boronate complexes is one of the most
representative reactions in boron chemistry. This process has been used extensively to …

This review discusses recent advances in the chemistry of saturated boronic acids,
boronates, and trifluoroborates. Applications of the title compounds in the design of boron …

An unprecedented visible-light-induced transition-metal-free alkynylation of alkyl pinacol
boronates has been demonstrated with alkynyl phenylsulfones as the alkynylation reagents …

Strategies that enable the efficient assembly of complex building blocks from feedstock
chemicals are of paramount importance to synthetic chemistry. Building upon the pioneering …

Benzothiophenes are valuable heterocycles that are widely used in medicines,
agrochemicals, and materials science. Herein, we report a general method for the synthesis …

Quaternary benzylic centers are accessed with high atom and step economy by Ir-catalyzed
alkene hydroarylation. These studies provide unique examples of the use of non-polarized …

A transition-metal-free direct trifluoromethylthiolation of the ipso-carbon of lithium aryl
boronates with trifluoromethanesulfenate under mild conditions was described. In addition …

An electrochemical cross-coupling reaction between arylboronic esters and aryllithiums was
developed. The presence of Br–in the electrolyte was found to be essential for the reaction …

The adsorption behavior of small molecules at solid–liquid interfaces have become an
important research topic in recent years. For example, small molecules of aniline pollutants …

This Thesis presents the development of multiple Ir (I)-catalysed hydrofunctionalisation
methodologies. Following the introduction of enantioselective intermolecular Murai-type …