Nonplanar porphyrins: synthesis, properties, and unique functionalities

T Ishizuka, N Grover, CJ Kingsbury, H Kotani… - Chemical Society …, 2022 - pubs.rsc.org
Porphyrins are variously substituted tetrapyrrolic macrocycles, with wide-ranging biological
and chemical applications derived from metal chelation in the core and the 18π aromatic …

Unsymmetrical β-functionalized 'push–pull'porphyrins: synthesis and photophysical, electrochemical and nonlinear optical properties

P Rathi, S Kumar, D Banerjee, VR Soma… - Dalton …, 2020 - pubs.rsc.org
Two new series of β-triphenylamine-appended porphyrins (MTPP (TPA) 2X,(where M= 2H,
Co (II), Ni (II), Cu (II), Zn (II) and X= NO2/CHO) have been synthesized and characterized by …

Investigations of low-symmetrical tetraaryltetrabenzoporphyrins produced by mixed condensation reactions

M Ruppel, LP Gazetas, D Lungerich… - The Journal of …, 2020 - ACS Publications
Within the past decade, tetraaryltetrabenzoporphyrins (TATBPs) have gained rising attention
due to their potential in various fields of materials science and medicinal chemistry …

Single Pyrrole Unit Functionalized Electron Deficient Porphyrins and Their Metal Complexes: Synthesis, Structural, Spectral and Electrochemical Properties

W Arif, R Kumar - ChemistrySelect, 2023 - Wiley Online Library
A family of electron‐deficient regioselective β‐disubstituted meso‐tetraphenylporphyrins,
H2TPP (R) 2 (where R= trifluoromethyl (CF3) and cyano (CN) and its metal complexes (Co …

Exploring the Electronic Influence of β‐Br Substitutions in CuTPP on Electrochemical Overall Water Splitting in Alkaline Medium

I Ahmad Lone, R Kumar - ChemistrySelect, 2022 - Wiley Online Library
Beta substitution has a marked influence on the electronic environment of porphyrin ring
atoms and the structure of the substituted porphyrin. In this work, we explore the influence of …

-Functionalized palladium(II) porphyrins: Facile synthesis, structural, spectral, and electrochemical redox properties

P Rathi, K Prakash, M Sankar - Journal of Porphyrins and …, 2023 - World Scientific
Two β-substituted Pd (II) porphyrins,(PdTPP (NO 2) Ph2 and PdTPP (Ph) 4), were
synthesized and characterized by various spectroscopic techniques, and their spectral and …

β-Diformyl porphyrins: Synthesis, structural, spectral and electrochemical properties

K Prakash, M Sankar - Journal of Porphyrins and Phthalocyanines, 2022 - World Scientific
Antipodal β-diformyl porphyrin (H2TPP (CHO) 2) and its metal complexes (MTPP (CHO) 2,
M= Co II, Ni II, Cu II, and Zn II) are synthesized and characterized by various spectroscopic …

Facile synthesis of antipodal β-arylaminodibromoporphyrins through Buchwald-Hartwig CN coupling reaction and exploring their spectral and electrochemical redox …

K Prakash, WR Osterloh, P Rathi, KM Kadish… - Journal of …, 2021 - Elsevier
A new family of antipodal β-arylaminodibromoporphyrins was synthesized through a
Buchwald-Hartwing CN coupling reaction and characterized as to its spectroscopic and …

Spectroelectrochemical one-electron reduction product of (TPP)Zn in nonaqueous media? Not always the expected porphyrin -anion radical

WR Osterloh, Y Fang, Z Ou… - Journal of Porphyrins and …, 2022 - World Scientific
Zinc tetraphenylporphyrin (TPP) Zn was examined as to its as to its electroreduction
properties by cyclic voltammetry and spectroelectrochemistry in six nonaqueous solvents …

[PDF][PDF] Alkyne Activation on Bio-inspired Tungsten-Complexes

LA Brandner - marshallplan.at
The tungsten-dependent enzyme acetylene hydratase catalyzes the non-redox reaction of
acetylene to acetaldehyde. Density functional theory (DFT) calculations were performed to …