Rhodium (III)-Catalyzed Anti-Markovnikov Hydroamidation of Unactivated Alkenes Using Dioxazolones as Amidating Reagents

N Wagner-Carlberg, T Rovis - Journal of the American Chemical …, 2022 - ACS Publications
The amide is one of the most prevalent functional groups in all of pharmaceuticals, and for
this reason, reactions that introduce the amide moiety are of particular value. Intermolecular …

Origin of the Boosting Effect of Polyoxometalates in Photocatalysis: The Case of CO2 Reduction by a Rh-Containing Metal–Organic Framework

A Solé-Daura, Y Benseghir, MH Ha-Thi… - ACS …, 2022 - ACS Publications
The immobilization of polyoxometalates (POMs) near catalytic centers of metal–organic
frameworks (MOFs) has been reported as an advantageous strategy to boost their …

Mechanistic roles of metal-and ligand-protonated species in hydrogen evolution with [Cp* Rh] complexes

WC Henke, Y Peng, AA Meier, E Fujita… - Proceedings of the …, 2023 - National Acad Sciences
Protonation reactions involving organometallic complexes are ubiquitous in redox chemistry
and often result in the generation of reactive metal hydrides. However, some organometallic …

Redox-induced structural reorganization dictates kinetics of cobalt (III) hydride formation via proton-coupled electron transfer

DA Kurtz, D Dhar, N Elgrishi, B Kandemir… - Journal of the …, 2021 - ACS Publications
Two-electron, one-proton reactions of a family of [CoCp (dxpe)(NCCH3)] 2+ complexes (Cp=
cyclopentadienyl, dxpe= 1, 2-bis (di (aryl/alkyl) phosphino) ethane) form the corresponding …

Highly selective in-situ prepared gC3N4/PB composite photocatalyst for direct CH bond arylation and NADH regeneration cofactor under solar light

N Swarnkar, RK Yadav, S Singh, R Shahin… - Journal of Chemical …, 2023 - Springer
Metal-free photocatalysis is a sustainable and environmentally friendly method of
transforming solar energy into molecules with added value. A light-harvesting photocatalyst …

Efficient nicotinamide adenine dinucleotide regeneration with a rhodium–carbene catalyst and isolation of a hydride intermediate

V Ganesan, JJ Kim, J Shin, K Park, S Yoon - Inorganic chemistry, 2022 - ACS Publications
Regeneration of nicotinamide adenine dinucleotide (NADH) has been the primary interest in
the field of enzymatic transformation, especially associating oxidoreductases given the …

Computational Insights into the Influence of Ligands on Hydrogen Generation with [Cp* Rh] Hydrides

T Balduf, JD Blakemore, M Caricato - The Journal of Physical …, 2023 - ACS Publications
This work reports a computational investigation of the effect of ancillary ligands on the
activity of an Rh catalyst for hydrogen evolution based on the [Cp* Rh] motif (Cp*= η5 …

Chemical and Electrochemical Properties of [Cp* Rh] Complexes Supported by a Hybrid Phosphine-Imine Ligand

JA Hopkins, D Lionetti, VW Day, JD Blakemore - Organometallics, 2018 - ACS Publications
A series of [Cp* Rh] complexes (Cp*= η5-pentamethylcyclopentadienyl) bearing the κ2-[P,
N]-8-(diphenylphosphino) quinoline (PQN) ligand have been prepared and characterized …

Isolation, characterization and reactivity of key intermediates relevant to reductive (electro) catalysis with Cp* Rh complexes containing pyridyl‐MIC (MIC= mesoionic …

T Bens, RRM Walter, J Beerhues… - … A European Journal, 2024 - Wiley Online Library
In recent years, metal complexes of pyridyl‐mesoionic carbene (MIC) ligands have been
reported as excellent homogeneous and molecular electrocatalysts. In combination with …

Supramolecular Photocatalyst with a Rh(III)-Complex Catalyst Unit for CO2 Reduction

D Ghosh, H Takeda, DC Fabry, Y Tamaki… - ACS Sustainable …, 2018 - ACS Publications
The development of supramolecular photocatalysts has been an important target in the field
of artificial photosynthesis because of their efficient reduction of CO2 and water oxidation …