Transition‐metal‐catalyzed copolymerization of olefins with polar monomers represents a
challenge because of the large variety of substrate‐induced side reactions. However, this …

Conspectus Polyolefins are produced in vast amounts and are found in so many consumer
products that the two most commonly produced forms, polyethylene (PE) and polypropylene …

Several nickel complexes bearing sterically bulky phosphino-phenolate ([P, O]) ligands were
synthesized and explored as catalysts for olefin (co) polymerization. In the absence of an …

Nickel‐and palladium‐catalyzed insertion copolymerization of ethylene and acrylate
comonomers for synthesis of ethylene‐acrylates copolymers have attracted much academic …

The efficient copolymerization of acrylates with ethylene using Ni catalysts remains a
challenge. Herein, we report two neutral Ni (II) catalysts (POP-Ni-py (1) and PONap-Ni-py …

Coordination insertion polymerization is unsurpassed as a straightforward method for
synthesis of high-value polyolefins by the copolymerization of ethylene and polar …

Group 10 metal catalysts have shown much promise for the copolymerization of nonpolar
with polar alkenes to directly generate functional materials, but access to high copolymer …

Polar monomer-induced β-H elimination is a key elementary step in polar polyolefin
synthesis by coordination polymerization but remains underexplored. Herein, we show that …

Polar polyolefin synthesis by coordination polymerization is of high interest, but the catalysts'
low activity limits industrial implementation. Herein, we demonstrate how the nature of the …

The replacement of precious metals in catalysis by earth‐abundant metals is currently one of
the urgent challenges for chemists. Whereas palladium‐catalyzed copolymerization of …