The Brook rearrangement has emerged as one of the most pivotal transformations in organic
chemistry, with broad applications spanning organic synthesis, drug design, and materials …

Small molecules find extensive application in medicine, food safety, and environmental
studies, particularly in biomedicine. Immunoassay technology, leveraging the specific …

Fused-cyclopropane ring-containing γ-lactone compounds are versatile building blocks in
many fields, including the synthesis of biologically active compounds. Here, we report the …

We report the reactivity of in situ-generated nucleophilic siloxycarbenes from acylsilanes via
the 1, 2-Brook rearrangement in the presence of visible light with heterocumulenes. This …

The insertion of carbene into secondary amide N–H bonds remains underexplored in
organic synthesis. In this work, we discovered the visible-light-induced insertion of …

Computational photochemistry provides a description of light-induced chemical phenomena
reaching the molecular size-scale and femtosecond time-scale resolutions. In the period …

In the introduction chapter we introduce the volume and its three sections, namely critical
reviews, highlights on recent “hot” topics and SPR lectures in photochemistry. Furthermore …

In this study, we explored the use of Mes‐Acr‐MeClO4 as a visible light photocatalyst for
multicomponent reactions involving quinoxalin‐2 (1H)‐ones with CBrCl3 and styrene. The …

A blue light-induced formal insertion reaction of α-siloxy carbene into the CH bond of 1, 3-
diketones has been reported. Under the irradiation of blue light, acylsilane converted to α …