Confusion is a novel concept of isomerism in porphyrin chemistry, delivering a steady
stream of new chemistry since the discovery of N-confused porphyrin, a porphyrin mutant, in …

The world of modified porphyrins changed forever when an N-confused porphyrin (NCP), a
porphyrin isomer, was first published in 1994. The replacement of one inner nitrogen with a …

Seventeen Cu complexes with formal oxidation states ranging from CuI to CuIII are
investigated through the use of multiedge X-ray absorption spectroscopy (XAS) and density …

A series of organometallic copper complexes in formal oxidation states ranging from+ 1 to+
3 have been characterized by a combination of Cu K-edge X-ray absorption (XAS) and Cu …

The σ-hole and π-hole interactions allow for a systematic understanding of some features of
the attractive interactions involving elements of groups 13–18 of the periodic table and of …

Organocopper (III) species were generally considered as the key intermediates in a variety
of copper-catalyzed cross-coupling reactions, aerobic oxidations, as well as enzyme …

The question of ligand noninnocence in Cu corroles has long been a topic of discussion.
Presented herein is a Cu K-edge X-ray absorption spectroscopy (XAS) study, which …

Biomass upgrading–the conversion of biomass waste into value-added products–provides a
possible solution to reduce global dependency on nonrenewable resources. This study …

Porphyrins and corroles are at the same time very similar and distinct species. Porphyrins
are present in nature and are well known by scientists for almost two centuries (1840) …

A 139-π-electron nanographenoid radical was obtained by expanding the periphery of a
naphthalimide–azacoronene hybrid with a methine bridge. The radical was isolated in the …