Reduction of NO by diiron complexes in relation to flavodiiron nitric oxide reductases
Reduction of nitric oxide (NO) to nitrous oxide (N2O) is associated with immense biological
and health implications. Flavodiiron nitric oxide reductases (FNORs) are diiron containing …
and health implications. Flavodiiron nitric oxide reductases (FNORs) are diiron containing …
Flavodiiron nitric oxide reductases: Recent developments in the mechanistic study and model chemistry for the catalytic reduction of NO
S Khatua, A Majumdar - Journal of Inorganic Biochemistry, 2015 - Elsevier
Inducible NO synthase in mammals helps to produce up to micromolar concentration of nitric
oxide (NO) which acts as a key immune defense agent to kill invading pathogens. In order to …
oxide (NO) which acts as a key immune defense agent to kill invading pathogens. In order to …
Nitrite Formation at a Diiron Dinitrosyl Complex
AL Poptic, JK Klinger, SL Carter… - Journal of the …, 2023 - ACS Publications
Pathogenic bacteria employ iron-containing enzymes to detoxify nitric oxide (NO•) produced
by mammals as part of their immune response. Two classes of diiron proteins, flavodiiron …
by mammals as part of their immune response. Two classes of diiron proteins, flavodiiron …
Synthesis and structure of a ferric complex of 2, 6-di (1 H-pyrazol-3-yl) pyridine and its excellent performance in the redox-controlled living ring-opening polymerization …
YY Fang, WJ Gong, XJ Shang, HX Li, J Gao… - Dalton …, 2014 - pubs.rsc.org
The reaction of FeCl3 with a pincer ligand, 2, 6-di (1H-pyrazol-3-yl) pyridine (bppyH2),
produced a mononuclear Fe (III) complex [Fe (bppyH2) Cl3](1), which could be reduced to …
produced a mononuclear Fe (III) complex [Fe (bppyH2) Cl3](1), which could be reduced to …
Functional Mononitrosyl Diiron(II) Complex Mediates the Reduction of NO to N2O with Relevance for Flavodiiron NO Reductases
Reaction of [Fe2 (N-Et-HPTB)(CH3COS)](BF4) 2 (1) with (NO)(BF4) produces a nonheme
mononitrosyl diiron (II) complex,[Fe2 (N-Et-HPTB)(NO)(DMF) 3](BF4) 3 (2). Complex 2 is the …
mononitrosyl diiron (II) complex,[Fe2 (N-Et-HPTB)(NO)(DMF) 3](BF4) 3 (2). Complex 2 is the …
Functional models for the mono-and dinitrosyl intermediates of FNORs: semireduction versus superreduction of NO
The reduction of NO to N2O by flavodiiron nitric oxide reductases (FNORs) is related to the
disruption of the defense mechanism in mammals against invading pathogens. The …
disruption of the defense mechanism in mammals against invading pathogens. The …
Reductive transformations of a pyrazolate-based bioinspired diiron–dinitrosyl Complex
N Kindermann, A Schober, S Demeshko… - Inorganic …, 2016 - ACS Publications
Flavo-diiron nitric oxide reductases (FNORs) are a subclass of nonheme diiron proteins in
pathogenic bacteria that reductively transform NO to N2O, thereby abrogating the nitrosative …
pathogenic bacteria that reductively transform NO to N2O, thereby abrogating the nitrosative …
C–S bond cleavage, redox reactions, and dioxygen activation by nonheme dicobalt (II) complexes
M Jana, A Majumdar - Inorganic Chemistry, 2018 - ACS Publications
Synthesis and reactivity of a series of thiolate/thiocarboxylate bridged dicobalt (II) complexes
were investigated in comparison with their carboxylate bridged analogues bearing free …
were investigated in comparison with their carboxylate bridged analogues bearing free …
A Monohydrosulfidodinitrosyldiiron Complex That Generates N2O as a Model for Flavodiiron Nitric Oxide Reductases: Reaction Mechanism and Electronic Structure
Flavodiiron nitric oxide reductases (FNORs) protect microbes from nitrosative stress under
anaerobic conditions by mediating the reduction of nitric oxide (NO) to nitrous oxide (N2O) …
anaerobic conditions by mediating the reduction of nitric oxide (NO) to nitrous oxide (N2O) …
Light-Induced N2O Production from a Non-heme Iron–Nitrosyl Dimer
Two non-heme iron–nitrosyl species,[Fe2 (N-Et-HPTB)(O2CPh)(NO) 2](BF4) 2 (1a) and [Fe2
(N-Et-HPTB)(DMF) 2 (NO)(OH)](BF4) 3 (2a), are characterized by FTIR and resonance …
(N-Et-HPTB)(DMF) 2 (NO)(OH)](BF4) 3 (2a), are characterized by FTIR and resonance …