Key tradeoffs limiting the performance of organic photovoltaics

I Ramirez, M Causa', Y Zhong… - Advanced Energy …, 2018 - Wiley Online Library
Abstract 2017 saw the publication of several new material systems that challenge the long‐
held notion that a driving force is necessary for efficient exciton dissociation in organic …

Molecular understanding of fullerene–electron donor interactions in organic solar cells

SM Ryno, MK Ravva, X Chen, H Li… - Advanced Energy …, 2017 - Wiley Online Library
Organic solar cells hold promise of providing low‐cost, renewable power generation, with
current devices providing up to 13% power conversion efficiency. The rational design of …

Impact of interfacial molecular orientation on radiative recombination and charge generation efficiency

NA Ran, S Roland, JA Love, V Savikhin… - Nature …, 2017 - nature.com
A long standing question in organic electronics concerns the effects of molecular orientation
at donor/acceptor heterojunctions. Given a well-controlled donor/acceptor bilayer system …

Importance of the donor: fullerene intermolecular arrangement for high-efficiency organic photovoltaics

KR Graham, C Cabanetos, JP Jahnke… - Journal of the …, 2014 - ACS Publications
The performance of organic photovoltaic (OPV) material systems are hypothesized to
depend strongly on the intermolecular arrangements at the donor: fullerene interfaces. A …

Impact of mesoscale order on open-circuit voltage in organic solar cells

C Poelking, M Tietze, C Elschner, S Olthof, D Hertel… - Nature materials, 2015 - nature.com
Structural order in organic solar cells is paramount: it reduces energetic disorder, boosts
charge and exciton mobilities, and assists exciton splitting. Owing to spatial localization of …

Energy-level alignment at organic heterointerfaces

M Oehzelt, K Akaike, N Koch, G Heimel - Science advances, 2015 - science.org
Today's champion organic (opto-) electronic devices comprise an ever-increasing number of
different organic-semiconductor layers. The functionality of these complex heterostructures …

[PDF][PDF] Effect of Molecular Packing and Charge Delocalization on the Nonradiative Recombination of Charge-Transfer States in Organic Solar Cells.

XK Chen, MK Ravva, H Li, SM Ryno… - Advanced Energy …, 2016 - researchgate.net
DOI: 10.1002/aenm. 201601325 nonradiative energy loss mechanisms is highly desirable.
We note that nonradiative recombination processes can also occur, for instance, because of …

Energetics of electron–hole separation at P3HT/PCBM heterojunctions

G D'Avino, S Mothy, L Muccioli, C Zannoni… - The Journal of …, 2013 - ACS Publications
The energetics of electron–hole separation at the prototypical donor–acceptor interface
P3HT/PCBM is investigated by means of a combination of molecular dynamics simulations …

Design rules for organic donor–acceptor heterojunctions: pathway for charge splitting and detrapping

C Poelking, D Andrienko - Journal of the American Chemical …, 2015 - ACS Publications
Organic solar cells rely on the conversion of a Frenkel exciton into free charges via a charge-
transfer state formed on a molecular donor–acceptor pair. These charge-transfer states are …

Interfacial disorder in efficient polymer solar cells: the impact of donor molecular structure and solvent additives

N Jain, N Chandrasekaran, A Sadhanala… - Journal of Materials …, 2017 - pubs.rsc.org
The performance of bulk heterojunction (BHJ) organic solar cells (OSCs) strongly depends
on the intermolecular packing of donor: acceptor (D: A) molecules, as it directly influences …