Synthesis of all-silica and high-silica molecular sieves in fluoride media

MA Camblor, LA Villaescusa, MJ Diaz-Cabanas - Topics in Catalysis, 1999 - Springer
Recent advances in the synthesis of all-silica and high-silica crystalline molecular sieves in
fluoride media, with special regard to low framework density phases, are presented. The …

Preparation and catalytic properties of new mesoporous materials

A Corma - Topics in Catalysis, 1997 - Springer
The development of ordered mesoporous solids is revised. Acid, base, and redox catalytic
properties are presented together with their application for a series of organic reactions of …

Topologically ordered amorphous silica obtained from the collapsed siliceous zeolite, silicalite-1-F: a step toward “perfect” glasses

J Haines, C Levelut, A Isambert, P Hébert… - Journal of the …, 2009 - ACS Publications
A dense amorphous form of silica was prepared at high pressure from the highly
compressible, siliceous zeolite, silicalite-1-F. Reverse Monte Carlo modeling of total X-ray …

Zeolite synthesis in fluoride media: structure direction toward ITW by small methylimidazolium cations

A Rojas, E Martínez-Morales… - Journal of the …, 2012 - ACS Publications
Pure silica ITW zeolite can be synthesized using 1, 2, 3-trimethylimidazolium and 1, 3-
dimethylimidazolium cations and fluoride anions as structure-directing agents (SDAs) …

Indigo@ Silicalite: a new organic− inorganic hybrid pigment

C Dejoie, P Martinetto, E Dooryhee… - … Applied Materials & …, 2010 - ACS Publications
In the search for stable and enduring organic colors, we have combined indigo, a historical
and industrially important chromophore, with silicalite, the MFI zeolite. The resulting pigment …

Zeolite structure direction by simple Bis (methylimidazolium) cations: the effect of the spacer length on structure direction and of the imidazolium ring orientation on the …

A Rojas, L Gómez-Hortigüela… - Journal of the American …, 2012 - ACS Publications
A series of doubly charged structure-directing agents based on two methylimidazolium
moieties linked by a linear bridge of n= 3, 4, 5, or 6 methylene groups has been used in the …

Fluoride removal from double four-membered ring (D4R) units in As-synthesized Ge-containing zeolites

X Liu, U Ravon, A Tuel - Chemistry of Materials, 2011 - ACS Publications
Fluoride anions can be removed from the framework of as-prepared Ge-containing zeolites
ITQ-13 and ITQ-17 without modification of the crystallinity and crystal habit. By contrast to all …

Host–guest stabilization of a zeolite strained framework: In situ transformation of zeolite MTW into the less dense and more strained ITW

A Rojas, ML San-Roman… - Chemistry of …, 2013 - ACS Publications
The new organic structure-directing agent 1-ethyl-2, 3-dimethylimidazolium, in conjuction
with fluoride anions, shows selectivity toward pure silica zeolite ITW. At low water contents …

Crystal structure of an indigo@ silicalite hybrid related to the ancient Maya blue pigment

C Dejoie, P Martinetto, N Tamura, M Kunz… - The Journal of …, 2014 - ACS Publications
The structure of the indigo@ silicalite pigment, an analog of ancient Maya Blue, has been
determined by combining X-ray Laue microdiffraction and powder diffraction techniques …

Association of indigo with zeolites for improved color stabilization

C Dejoie, P Martinetto, E Dooryhee… - Applied …, 2010 - opg.optica.org
The durability of an organic color and its resistance against external chemical agents and
exposure to light can be significantly enhanced by hybridizing the natural dye with a mineral …