Transition-metal-catalyzed C–H activation has developed a contemporary approach to the
omnipresent area of retrosynthetic disconnection. Scientific researchers have been tempted …

Disproportionation and comproportionation reactions have become increasingly important
electron transfer events in organometallic chemistry and catalysis. The renewed interest in …

Thiol is known to act as a hydrogen atom transfer catalyst working in synergy with a
photocatalyst in photoredox catalysis, but we report herein that an arene thiolate with an …

Organofluorine compounds have attracted extensive attention in various industrial fields due
to their unique chemical and physical properties. Despite increasing demand in a wide …

Fluorine‐containing moieties are widely used in the pharmaceutical, agrochemical, and
material fields. Thus, these structures are of immense interest in the fields of organic …

Chiral α-aryl N-heterocycles are commonly found in natural products, pharmaceutical
agents, and chiral catalysts but remain challenging to access via asymmetric catalysis …

The activation and functionalization of C–F bonds under mild conditions can serve as an
important tool for organic syntheses including the modification of pharmaceuticals and …

Herein we report a chromium-catalyzed allylic defluorinative ketyl olefin coupling between
aldehydes and α-trifluoromethyl alkenes, which provides novel and efficient access to …

Much progress has been made in the development of methods to both create compounds
that contain C− F bonds and to functionalize C− F bonds. As such, C− F bonds are becoming …

A metal free, visible-light driven α-C (sp3)–H gem-difluoroallylation of glycine derivatives
with trifluoromethyl alkenes and 1, 3-enynes is presented. This protocol features mild and …