How palladium inhibits CO poisoning during electrocatalytic formic acid oxidation and carbon dioxide reduction
Abstract Development of reversible and stable catalysts for the electrochemical reduction of
CO2 is of great interest. Here, we elucidate the atomistic details of how a palladium …
CO2 is of great interest. Here, we elucidate the atomistic details of how a palladium …
Influence of Cations on HCOOH and CO Formation during CO2 Reduction on a PdMLPt(111) Electrode
Understanding the role of cations in the electrochemical CO2 reduction (CO2RR) process is
of fundamental importance for practical application. In this work, we investigate how cations …
of fundamental importance for practical application. In this work, we investigate how cations …
The progress in understanding the mechanisms of methanol and formic acid electrooxidation on platinum group metals (a review)
OA Petrii - Russian Journal of Electrochemistry, 2019 - Springer
The reactions of electrooxidation of methanol and formic acid pertain to the most important
model electrocatalytic processes and are used in direct low-temperature fuel cells. The …
model electrocatalytic processes and are used in direct low-temperature fuel cells. The …
Tunable periodically ordered mesoporosity in palladium membranes enables exceptional enhancement of intrinsic electrocatalytic activity for formic acid oxidation
Developing superior electrocatalysts for formic acid oxidation (FAO) is the most crucial step
in commercializing direct formic acid fuel cells. Herein, we electrodeposited palladium …
in commercializing direct formic acid fuel cells. Herein, we electrodeposited palladium …
Subsurface Hydride Formation Leads to Slow Surface Adsorption Processes on a Pd (111) Single-Crystal Electrode in Acidic Electrolytes
Palladium is one of the most important catalysts due to its widespread use in heterogeneous
catalysis and electrochemistry. However, an understanding of the electrochemical …
catalysis and electrochemistry. However, an understanding of the electrochemical …
A hybrid FeOx/CoOx/Pt ternary nanocatalyst for augmented catalysis of formic acid electro-oxidation
Platinum-based catalysts that have long been used as the anodes for the formic acid electro-
oxidation (FAO) in the direct formic acid fuel cells (DFAFCs) were susceptible to …
oxidation (FAO) in the direct formic acid fuel cells (DFAFCs) were susceptible to …
Adsorption processes on a Pd monolayer-modified Pt (111) electrode
Specific adsorption of anions is an important aspect in surface electrochemistry for its
influence on reaction kinetics in either a promoted or inhibited fashion. Perchloric acid is …
influence on reaction kinetics in either a promoted or inhibited fashion. Perchloric acid is …
Fluidized electrocatalysis
Particle-based electrocatalysts need to be glued on an electrode, where fast and slow steps
of the reaction are spatially and temporally convoluted near the particles. Since the particles …
of the reaction are spatially and temporally convoluted near the particles. Since the particles …
Preparation and identification of a novel 1, 1′-(1, 4-phenylenebis (methylene) bis (4-cyanopyridin-1-ium) bromide as a corrosion inhibitor for C1018 in highly acidic …
Abstract 1, 1′-(1, 4-phenylene-bis (methylene)) bis (4-cyanopyridin-1-ium) bromide (PCB)
was synthesized and identified via spectral methods: Fourier-transform infrared (FTIR) …
was synthesized and identified via spectral methods: Fourier-transform infrared (FTIR) …
The high Tafel slope and small potential dependence of activation energy for formic acid oxidation on a Pd electrode
N Uwitonze, D Zhou, J Lei, W Chen, XQ Zuo, J Cai… - Electrochimica …, 2018 - Elsevier
Formic acid oxidation (FAO) on Pd electrode at various temperatures is investigated by
cyclic voltammetry, potential step chronoamperometry and electrochemical in situ infrared …
cyclic voltammetry, potential step chronoamperometry and electrochemical in situ infrared …