In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …

Glycosyl radical functionalization is one of the central topics in synthetic carbohydrate
chemistry. Recent advances in metal‐catalyzed cross‐coupling chemistry and …

Iron as an important element plays crucial roles in various physiological and pathological
processes. Iron metabolism behaves in systemic and cellular two levels that usually are in …

Aryl C-glycosides are an important class of carbohydrate derivatives, with widespread
application in drug development, biochemistry and material sciences. However, their …

C‐aryl glycosyl compounds offer better in vivo stability relative to O‐and N‐glycoside
analogues. C‐aryl glycosides are extensively investigated as drug candidates and applied …

Conspectus Efficient construction of ubiquitous carbon–carbon bonds between two
electrophiles has garnered interest in recent decades, particularly if it is mediated by …

Here we report a nonenzymatic glycosylation reaction that builds axial S-glycosidic bonds
under biorelevant conditions. This strategy is enabled by the design and use of allyl glycosyl …

Stereochemically defined C-glycosides are prized for their biological activity. Developing a
catalytic method that comprises non-precious metals to synthesize these C-glycosides …

Identifying a general bench-stable precursor of multifunctional sugar residues that is also
amenable to further activation under mild conditions remains a great challenge in …

The scarcity of precious metals has led to the development of sustainable strategies for
metal‐catalyzed cross‐coupling reactions. The establishment of new catalytic methods …