We lay the foundation of a circuit theory for chemical reaction networks. Chemical reactions are grouped into chemical modules solely characterized by their current-concentration …
We generalize the thermodynamic uncertainty relation (TUR) and thermodynamic speed limit (TSL) for deterministic chemical reaction networks (CRNs). The scaled diffusion …
Information thermodynamics relates the rate of change of mutual information between two interacting subsystems to their thermodynamics when the joined system is described by a …
All current formulations of nonequilibrium thermodynamics of open chemical reaction networks rely on the assumption of non-interacting species. We develop a general theory …
Current formulations of nonequilibrium thermodynamics of open chemical reaction networks only consider chemostats as free-energy sources sustaining nonequilibrium behaviors …
A Wachtel, R Rao, M Esposito - The Journal of Chemical Physics, 2022 - pubs.aip.org
We provide a rigorous definition of free-energy transduction and its efficiency in arbitrary— linear or nonlinear—open chemical reaction networks (CRNs) operating at a steady state …
Diffusive dynamics in presence of deep energy minima and weak nongradient forces can be coarse grained into a mesoscopic jump process over the various basins of attraction …
Energy transduction is central to living organisms, but the impact of enzyme regulation and signaling on its thermodynamic efficiency is generally overlooked. Here, we analyze the …
L Peng, L Hong - Physical Review Research, 2024 - APS
The partial equilibrium approximation (PEA) and the quasi-steady-state approximation (QSSA) are two classical methods for reducing complex macroscopic chemical reactions …