Recent advances in our mechanistic understanding of dye-sensitized electron transfer reactions occurring at metal oxide interfaces are described. These advances were enabled …
Aryl diazonium salts are ubiquitous building blocks in chemistry, as they are useful radical precursors in organic synthesis as well as for the functionalization of solid materials. They …
The rapid development of photo (redox) catalysis within the last decades is remarkable to the extent that the utilization of light‐driven processes in organic chemistry has become a …
The application of organic photocatalysts towards the oxidation of pollutants in water is hampered by different limitations such as their insolubility in the media. Herein, we report …
Ion-pair interactions between a cationic ruthenium complex,[Ru (dtb) 2 (dea)][PF6] 2, C1 2+ where dea is 4, 4′-diethanolamide-2, 2′-bipyridine and dtb is 4, 4′-di-tert-butyl-2, 2 …
A comparative study of mesoporous thin films based on SnO2 (rutile) and TiO2 (anatase) nanocrystallites sensitized to visible light with [Ru (dtb) 2 (dcb)](PF6) 2, where dtb= 4, 4 …
Photodriven HCl splitting to produce solar fuels is an important goal that requires strong photo-oxidants capable of chloride oxidation. In a molecular approach toward this goal …
Recombination of electrons injected into TiO2 with molecular acceptors present at the interface represents an important loss mechanism in dye-sensitized water oxidation and …
Two sensitizers,[Ru (bpy) 2 (dcb)] 2+(RuC) and [Ru (bpy) 2 (dpb)] 2+(RuP), where bpy is 2, 2′-bipyridine, dcb is 4, 4′-dicarboxylic acid-2, 2′-bipyridine and dpb is 4, 4 …