This article sets out to review the chemistry relating to the synthesis of structural and
functional analogues of the three classes of hydrogenases. This chemistry has grown …

Phosphorus-based Mannich-type reactions (phospha-Mannich reactions) of primary or
secondary phosphines with carbonyl compounds and amines (R2NH, RNH2, and NH3) …

A Ni (II) bisphosphine dithiolate compound degrades into an electrode-adsorbed film that
can evolve hydrogen under reducing and protic conditions. An electrochemical study …

Electrochemical hydrogenation of a homogeneous nickel complex to form a surface
adsorbed hydrogen-evolving species - Chemical Communications (RSC Publishing) DOI:10.1039/C4CC08662G …

A series of mixed-valence nickel–iron dithiolates is described. Oxidation of (diphosphine) Ni
(dithiolate) Fe (CO) 3 complexes 1, 2, and 3 with ferrocenium salts affords the corresponding …

The complex [Ni (PCy2NBz2) 2](BF4) 2, 1, reacts rapidly and reversibly with carbon
monoxide (1 atm) at 25° C to form [Ni (CO)(PCy2NBz2) 2](BF4) 2, 2, which has been …

Inspired by the metal active sites of [FeFe]-and [NiFe]‑hydrogenases, a series of
mononuclear Ni (II) ethanedithiolate complexes [{(Ph 2 PCH 2) 2×} Ni (SCH 2 CH 2 S)](X …

Dimeric (N2S) Ni complexes and the monomeric N2S2 bismercaptodiazacycloheptane
nickel complex,(bme-dach) Ni, serve as precursors to two N2-, N′-/S-complexes where …

The tungsten complex W [SNS] 2 ([SNS] H3= bis (2-mercapto-4-methylphenyl) amine) was
bound to a Ni (dppe)[dppe= 1, 2-bis (diphenylphosphino) ethane] fragment to form the new …

With the objective of gaining insight into the modulation of the reduction potential of the Ni
(II/I) couple, we have synthesized two mononuclear nickel (II) complexes, NiLen (H2Len= N …