Catalytic reactions of C–C and C–X bond formation are discussed in this critical review with
particular emphasis on cross coupling reactions catalyzed by palladium and wide bite angle …

Palladium‐catalyzed carbonylation reactions of alkenes and alkynes with different
nucleophiles have undergone rapid development ever since the seminal work of Reppe …

The field of multimetallic catalysis is rapidly developing and some multimetallic complexes
catalyze organic transformations to yield the desired products in more efficient ways owing …

Small molecules that modulate the 14-3-3 protein–protein interaction (PPI) network
represent valuable therapeutics and tool compounds. However, access has been lost to 14 …

In 1961, a report in the Journal of the American Chemical Society detailed the synthesis of a
lemon-yellow compound asssigned as the organometallic complex trans-[IrCl (CO)(PPh3) …

Carbonylation reactions of alkenes constitute the most important industrial processes in
homogeneous catalysis. Despite the tremendous progress in this transformation, the …

Hemilabile ligands–ligands containing two or more potential donors to a metal centre, of
which one or more can dissociate–have the ability to provide a transition metal complex with …

The bidentate phosphine ligand 1, 2-bis (di-tert-butylphosphinomethyl) benzene (1, 2-
DTBPMB) has been reported over the years as being one of, if not the, best ligands for …

A method for the Pd-catalyzed carbonylation of aryl bromides has been developed using
Xantphos as the ligand. This method is effective for the direct synthesis of Weinreb amides …

We report a catalyst for intermolecular hydroamination of vinylarenes that is substantially
more active for this process than catalysts published previously. With this more reactive …