The combination of photoredox and transition metal catalysis, which is termed
metallaphotoredox catalysis, is a powerful platform for building complex molecules under …

The functionalization of C–H bonds in organic molecules containing functional groups has
been one of the holy grails of catalysis. One synthetically important approach to the diverse …

Organoboron compounds are versatile intermediate for a diverse range of synthetic
transformations. The development of methodologies for the synthesis of organoboron …

This report describes the unprecedented electrooxidation of a solvent (eg, DMF)‐ligated
B2cat2 complex, whereby a solvent‐stabilized boryl radical is formed via quasi‐homolytic …

Abstract gem‐Diborylalkanes are highly valuable building blocks in organic synthesis and
pharmaceutical chemistry due to their ability to participate in multi‐step cross‐coupling …

The development of boron reagents is crucial for synthetic chemistry. Herein, we present a
scalable and practical synthesis of diborodichloromethane (DBDCM) through the reaction of …

General methods for the preparation of geminal bis (boronates) are of great interest due to
their widespread applications in organic synthesis. While the terminal gem‐diboron …

C–H bond activation and functionalization has been the subject of intensive research efforts
in organic synthesis due to their special relevance both academically and industrially. In …

Aldehyde decarbonylation has been extensively investigated, primarily using noble-metal
catalysts; however, nonprecious-base-metal-catalyzed aldehyde decarbonylation has been …

Organoboron chemistry has become a cornerstone of modern synthetic methodology. Most
of these reactions use an organoboron starting material that contains just one C (sp 2)–B or …