It is established that new reactive anionic palladium (0) complexes species are formed in
which palladium (0) is ligated by either chloride ions: Pd (0)(PPh3) 2Cl−(when generated by …

The ligand dba plays a crucial role both on the structure and on the reactivity of palladium
(0) complexes generated in situ in mixtures of Pd (dba) 2 and phosphine ligands. Whatever …

The completely revised third edition of this four-volume classic is fully updated and now
includes such topics as as CH-activation and multicomponent reactions. It describes the …

Ylide‐functionalized phosphine ligands (YPhos) were rationally designed to fit the
requirements of Buchwald–Hartwig aminations at room temperature. This ligand class …

Mixtures of Pd (dba) 2+ 2L-L (where LL is a bidentate ligand such as dppm, dppe, dppp,
dppb, dppf, and DIOP) lead to the formation of Pd (LL) 2 complexes which do not undergo …

Oxidative addition of different imidazolium cations to zerovalent group 10 metals, to afford
heterocyclic carbene complexes, has been investigated by both density functional theory …

The phenyl backbone-derived P, O-ligands 1 and 2 were investigated for their utility as
ligands in palladium/ligand-catalyzed Suzuki reactions. The 2-(2 ' …

Organofluorine compounds are widely used in all aspects of the chemical industry. Although
tetrafluoroethylene (TFE) is an example of an economical bulk organofluorine feedstock, the …

Palladium complexes with chiral phosphinooxazoline ligands are efficient catalysts for
enantioselective Heck reactions with aryl or alkenyl triflates and cyclic olefins. In the …

π-Acidic alkene (olefin) ligands positively influence Pd-catalysed cross-coupling processes,
interacting with both palladium (0) and palladium (II) species, in some cases stabilising key …