Electronic control over site-selectivity in hydrogen atom transfer (HAT) based C (sp 3)–H functionalization promoted by electrophilic reagents
M Galeotti, M Salamone, M Bietti - Chemical Society Reviews, 2022 - pubs.rsc.org
The direct functionalization of C (sp3)–H bonds represents one of the most investigated
approaches to develop new synthetic methodology. Among the available strategies for …
approaches to develop new synthetic methodology. Among the available strategies for …
Recent advances in C–H functionalisation through indirect hydrogen atom transfer
FS Meger, JA Murphy - Molecules, 2023 - mdpi.com
The functionalisation of C–H bonds has been an enormous achievement in synthetic
methodology, enabling new retrosynthetic disconnections and affording simple synthetic …
methodology, enabling new retrosynthetic disconnections and affording simple synthetic …
Role of Steric Effects on Rates of Hydrogen Atom Transfer Reactions
The influence of steric effects on the rates of hydrogen atom transfer (HAT) reactions
between oxyradicals and alkanes is explored computationally. Quantum chemical density …
between oxyradicals and alkanes is explored computationally. Quantum chemical density …
Radical and Cationic Pathways in C(sp3)–H Bond Oxygenation by Dioxiranes of Bicyclic and Spirocyclic Hydrocarbons Bearing Cyclopropane Moieties
M Galeotti, W Lee, S Sisti, M Casciotti… - Journal of the …, 2023 - ACS Publications
A product and DFT computational study on the reactions of 3-ethyl-3-(trifluoromethyl)
dioxirane (ETFDO) with bicyclic and spirocyclic hydrocarbons bearing cyclopropyl groups …
dioxirane (ETFDO) with bicyclic and spirocyclic hydrocarbons bearing cyclopropyl groups …
Factors Governing Reactivity and Selectivity in Hydrogen Atom Transfer from C(sp3)–H Bonds of Nitrogen-Containing Heterocycles to the Cumyloxyl Radical
M Galeotti, C Trasatti, S Sisti… - The Journal of Organic …, 2022 - ACS Publications
A kinetic study of the hydrogen atom transfer (HAT) reactions from nitrogen-containing
heterocycles (secondary and tertiary lactams, 2-imidazolidinones, 2-oxazolidinones, and …
heterocycles (secondary and tertiary lactams, 2-imidazolidinones, 2-oxazolidinones, and …
tert‐Butyl as a Functional Group: Non‐Directed Catalytic Hydroxylation of Sterically Congested Primary C−H Bonds
The tert‐butyl group is a common aliphatic motif extensively employed to implement steric
congestion and conformational rigidity in organic and organometallic molecules. Because of …
congestion and conformational rigidity in organic and organometallic molecules. Because of …
Resolving Oxygenation Pathways in Manganese-Catalyzed C(sp3)–H Functionalization via Radical and Cationic Intermediates
M Galeotti, L Vicens, M Salamone… - Journal of the …, 2022 - ACS Publications
The C (sp3)–H bond oxygenation of the cyclopropane-containing mechanistic probes 6-tert-
butylspiro [2.5] octane and spiro [2.5] octane with hydrogen peroxide catalyzed by …
butylspiro [2.5] octane and spiro [2.5] octane with hydrogen peroxide catalyzed by …