Electro-optical π-radicals: design advances, applications and future perspectives

P Murto, H Bronstein - Journal of Materials Chemistry C, 2022 - pubs.rsc.org
The unique open-shell electronic structure of neutral π-radicals has inspired research on
novel molecular materials for over a century. In recent years, rapid development in carbon …

Non-alternant non-benzenoid kekulenes: the birth of a new kekulene family

H Miyoshi, S Nobusue, A Shimizu, Y Tobe - Chemical Society Reviews, 2015 - pubs.rsc.org
“Kekulene” is a doughnut-like shaped polycyclic aromatic hydrocarbon consisting of
cyclically arrayed benzene rings. It has attracted a great deal of theoretical interest because …

Dinor [7] helicene and Beyond: Divergent Synthesis of Chiral Diradicaloids with Variable Open‐Shell Character

A Borissov, PJ Chmielewski… - Angewandte Chemie …, 2023 - Wiley Online Library
Diradicaloid helicenes constructed formally by non‐benzenoid double π‐extension of
phenanthrene were synthesized by a common strategy involving double electrophilic …

Higher order π-conjugated polycyclic hydrocarbons with open-shell singlet ground state: Nonazethrene versus nonacene

R Huang, H Phan, TS Herng, P Hu… - Journal of the …, 2016 - ACS Publications
Higher order acenes (ie, acenes longer than pentacene) and extended zethrenes (ie,
zethrenes longer than zethrene) are theoretically predicted to have an open-shell singlet …

Synthesis, Aromaticity, and Application of peri‐Pentacenopentacene: Localized Representation of Benzenoid Aromatic Compounds

T Jousselin‐Oba, M Mamada, K Wright… - Angewandte Chemie …, 2022 - Wiley Online Library
We report the synthesis and optoelectronic properties of TIPS‐peri‐pentacenopentacene
(TIPS‐PPP), a vertical extension of TIPS‐pentacene (TIPS‐PEN) and a low‐band‐gap …

Toward tetraradicaloid: the effect of fusion mode on radical character and chemical reactivity

P Hu, S Lee, TS Herng, N Aratani… - Journal of the …, 2016 - ACS Publications
Open-shell singlet diradicaloids display unique electronic, nonlinear optical, and magnetic
activity and could become novel molecular materials for organic electronics, photonics, and …

5,14-Diaryldiindeno[2,1-f:1′,2′-j]picene: A New Stable [7]Helicene with a Partial Biradical Character

YC Hsieh, CF Wu, YT Chen, CT Fang… - Journal of the …, 2018 - ACS Publications
5, 14-Diaryldiindeno [2, 1-f: 1′, 2′-j] picene (DDP, 1), a thermally and chemically stable
helical arene, can be prepared from 1, 4-bis [2-(arylethynyl) phenyl] benzene in four …

Non‐Alternant Non‐Benzenoid A romatic C ompounds: Past, Present, and Future

Y Tobe - The Chemical Record, 2015 - Wiley Online Library
The development of the chemistry of non‐alternant non‐benzenoid hydrocarbons is
reviewed in connection with the I nternational S ymposium on N ovel A romatic C ompounds …

Indacenodibenzothiophenes: synthesis, optoelectronic properties and materials applications of molecules with strong antiaromatic character

JL Marshall, K Uchida, CK Frederickson, C Schütt… - Chemical …, 2016 - pubs.rsc.org
Indeno [1, 2-b] fluorenes (IFs), while containing 4n π-electrons, are best described as two
aromatic benzene rings fused to a weakly paratropic s-indacene core. In this study, we find …

A Stable Saddle‐Shaped Polycyclic Hydrocarbon with an Open‐Shell Singlet Ground State

J Ma, J Liu, M Baumgarten, Y Fu, YZ Tan… - Angewandte Chemie …, 2017 - Wiley Online Library
Diindeno‐fused bischrysene, a new diindeno‐based polycyclic hydrocarbon (PH), was
synthesized and characterized. It was elucidated in detailed experimental and theoretical …