Bicyclic (alkyl)(amino) carbenes (BICAACs): synthesis, characteristics, and applications
Carbenes in general and isolable NHCs (N-heterocyclic carbenes) in particular have been
useful ligands in recent years. The emergence of CAACs [cyclic (alkyl)(amino) carbenes] …
useful ligands in recent years. The emergence of CAACs [cyclic (alkyl)(amino) carbenes] …
Photothermal Aza‐Michael Addition of Divergent Amines to Vinyl Sulfones: A Method Towards Transition Metal‐and Base‐Free Medium
T Duraisamy, K Govindan… - Asian Journal of …, 2023 - Wiley Online Library
A highly efficient and versatile method has been developed for the photothermal aza‐
Michael addition, producing β‐amino sulfones with excellent yields. The protocol uses mild …
Michael addition, producing β‐amino sulfones with excellent yields. The protocol uses mild …
Synthesis of Cyclic (Alkyl)(amino) carbene-Stabilized Copper–Iron Heterobimetallic Complexes and Their Application in Pyridine Hydroboration
In this report, we synthesized heterobimetallic complexes supported by cyclic and bicyclic
(alkyl)(amino) carbenes (CAAC and Et BICAAC)[(Me2 CAAC) CuFe (η5-C5H5)(CO) 2](1) …
(alkyl)(amino) carbenes (CAAC and Et BICAAC)[(Me2 CAAC) CuFe (η5-C5H5)(CO) 2](1) …
Cobalt (II) catalyzed Michael-type hydroamination of activated olefins
R Rajesh, JP Devassy, R Nihala… - Synthetic …, 2024 - Taylor & Francis
The aza-Michael addition reaction of primary and secondary amines to α, β-unsaturated
olefins viz; acrylonitrile, phenyl vinyl sulfone and dimethyl maleate has been carried out …
olefins viz; acrylonitrile, phenyl vinyl sulfone and dimethyl maleate has been carried out …
Lanthanoids in Hydroarylaminations: Yb (III)-and Tb (III)-Catalyzed Addition of Arylamines to Activated Olefins
R Rajesh, OK Sandhya, SP Narayanan… - Synthesis, 2024 - thieme-connect.com
Michael-type hydroaminations of acrylonitrile, phenyl vinyl sulfone, and dimethyl maleate
were realized using arylamines catalyzed independently by Yb (OTf) 3 and Tb (OTf) 3 to give …
were realized using arylamines catalyzed independently by Yb (OTf) 3 and Tb (OTf) 3 to give …
Homogeneous Copper Catalysts for Hydrogenation and Hydrofunctionalizations of Carbonyl Compounds, CO2, C= C Bonds, and Alkynes
JA Garduño, JJ Garcia - ChemCatChem - Wiley Online Library
Homogeneous hydrogenations and hydrofunctionalizations of carbon‐oxygen and carbon‐
carbon bonds with copper catalysts are reviewed herein. The title literature revision covers …
carbon bonds with copper catalysts are reviewed herein. The title literature revision covers …