Selective hydrogenolysis of glycerol to propylene glycol by using Cu: Zn: Cr: Zr mixed metal oxides catalyst

RV Sharma, P Kumar, AK Dalai - Applied Catalysis A: General, 2014 - Elsevier
Hydrogeneolysis of glycerol to propylene glycol has high interest due to cost and ease of
availability of glycerol. In this study, Cu: Zn: Cr: Zr based catalyst was used for selective …

Influence of the niobium supported species on the catalytic dehydration of glycerol to acrolein

C García-Sancho, JA Cecilia, A Moreno-Ruiz… - Applied Catalysis B …, 2015 - Elsevier
The present work deals with the catalytic performance of a series of supported niobium
oxide (1–12 wt% Nb 2 O 5) catalysts in the gas phase dehydration of glycerol. The niobium …

Promoting effect of zirconium oxide on Cu–Al 2 O 3 catalyst for the hydrogenolysis of glycerol to 1, 2-propanediol

F Cai, W Zhu, G Xiao - Catalysis Science & Technology, 2016 - pubs.rsc.org
In this work, ZrO2-promoted Cu–Al2O3 catalysts prepared by the co-precipitation method
were used for the hydrogenolysis of glycerol to 1, 2-propanediol in a fixed-bed reactor …

Active sites in modified copper catalysts for selective liquid phase dehydration of aqueous glycerol to acetol

RB Mane, A Yamaguchi, A Malawadkar, M Shirai… - RSC Advances, 2013 - pubs.rsc.org
We report here the influence of oxides of various metals viz. Ba, Mg, Zr, Zn, Al, and Cr in
modified copper catalysts, on the formation of different copper species and acid sites …

Continuous dehydration and hydrogenolysis of glycerol over non-chromium copper catalyst: Laboratory-scale process studies

RB Mane, CV Rode - Organic Process Research & Development, 2012 - ACS Publications
A non-chromium Cu: Al catalyst was developed for glycerol dehydration under N2
atmosphere to acetol and hydrogenolysis to 1, 2-propanediol (1, 2-PDO). Among the various …

[HTML][HTML] Gas-phase conversion of glycerol to acetol: Influence of support acidity on the catalytic stability and copper surface properties on the activity

TP Braga, N Essayem, S Prakash… - Journal of the Brazilian …, 2016 - SciELO Brasil
Mesoporous mixed copper-aluminum oxides and copper-silicon oxides were synthesized
with polymeric precursors route in order to evaluate the effect of the support acidity on the …

Influence of HZSM5 on the activity of Ru catalysts and product selectivity during the hydrogenolysis of glycerol

Y Li, L Ma, H Liu, D He - Applied Catalysis A: General, 2014 - Elsevier
The influence of the acidity of HZSM5 (X)(X= SiO 2/Al 2 O 3 ratios) on the activity of Ru
catalysts and product selectivity (particularly during the formation of methane by-products) in …

Aluminum doped mesoporous silica SBA-15 for glycerol dehydration to value-added chemicals

JA Cecilia, C García-Sancho, JM Mérida-Robles… - Journal of Sol-Gel …, 2017 - Springer
A series of Al-grafted mesoporous SBA-15 silica was synthesized and tested as catalysts in
the gas-phase dehydration of glycerol to acrolein. Different Si/Al molar ratios were employed …

Conversion of glycerol to acrolein by mesoporous sulfated zirconia-silica catalyst

H Kobayashi, S Ito, K Hara, A Fukuoka - Chinese Journal of Catalysis, 2017 - Elsevier
A mesoporous sulfated zirconia-silica catalyst bearing only Brønsted acid sites converted
glycerol to acrolein in 81% yield with 82% selectivity. Space time yield as high as 9.0 mmol …

中孔硫酸化氧化锆-氧化硅催化甘油转化制丙烯醛

H Kobayashi, S Ito, K Hara, A Fukuoka - 催化学报, 2017 - cjcatal.com
一种中孔硫酸化的, 只含Brø; nsted 酸位的氧化锆-氧化硅催化剂可将甘油转化为丙烯醛,
其产率和选择性分别为81% 和82%. 即使在低温(523 K) 下, 产物时空收率可高达9.0 mmol h-1 …