Mechanism of Propylene Polymerization with MgCl2-Supported Ziegler–Natta Catalysts Based on Counting of Active Centers: The Role of External Electron Donor
X Shen, Z Fu, J Hu, Q Wang, Z Fan - The Journal of Physical …, 2013 - ACS Publications
Four R1R2Si (OMe) 2 type compounds were added as an external electron donor (De) in
propylene polymerization with TiCl4/Di/MgCl2 type supported Ziegler–Natta catalysts (Di …
propylene polymerization with TiCl4/Di/MgCl2 type supported Ziegler–Natta catalysts (Di …
Copolymerization of propene and higher α‐olefins with the metallocene catalyst Et[Ind]2HfCl2/methylaluminoxane
M Arnold, O Henschke, J Knorr - … Chemistry and Physics, 1996 - Wiley Online Library
Copolymerizations of propene with higher α‐olefins including 1‐butene, 1‐hexene, 1‐
octene, 1‐dodecene and 1‐hexadecene were carried out with an isospecific metallocene …
octene, 1‐dodecene and 1‐hexadecene were carried out with an isospecific metallocene …
Process to produce low viscosity poly-alpha-olefins
MM Wu, CL Coker, JF Walzer Jr, P Jiang - US Patent 8,207,390, 2012 - Google Patents
US PATENT DOCUMENTS 2.978. 442 A 4/1961 Brightbill et al. 3,149,178 A 9, 1964
Hamilton et al. 3,164,578 A 1/1965 Baker et al. 3,382.291 A 5, 1968 Brennan 3,742,082 A 6 …
Hamilton et al. 3,164,578 A 1/1965 Baker et al. 3,382.291 A 5, 1968 Brennan 3,742,082 A 6 …
Distribution of active centers on TiCl4/MgCL2 catalyst for olefin polymerization
Z Fan, LX Feng, SL Yang - Journal of Polymer Science Part A …, 1996 - Wiley Online Library
Octene was polymerized with TiCl4/MgCl2—AlEt3 and the polymerization was quenched
with CH3COCl to introduce a CH3CO—group onto each propagation chain. The polymer …
with CH3COCl to introduce a CH3CO—group onto each propagation chain. The polymer …
Polyalpha-olefin compositions and processes to produce the same
MMS Wu, LS Baugh, JAM Canich, CS Chee… - US Patent …, 2014 - Google Patents
This invention relates to a polyalpha-olefin (and hydroge nated analogs thereof) comprising
more than 50 mole% of one or more C5 to C24 alpha-olefin monomers where the polyalpha …
more than 50 mole% of one or more C5 to C24 alpha-olefin monomers where the polyalpha …
Process to produce high viscosity fluids
MMS Wu, CL Coker, JF Walzer Jr, P Jiang… - US Patent …, 2011 - Google Patents
US7989670B2 - Process to produce high viscosity fluids - Google Patents US7989670B2 -
Process to produce high viscosity fluids - Google Patents Process to produce high viscosity …
Process to produce high viscosity fluids - Google Patents Process to produce high viscosity …
Process to produce polyalphaolefins
MM Wu, MP Hagemeister, N Yang - US Patent 8,513,478, 2013 - Google Patents
Liquid poly-alpha-ole? ns having a KVloo of 2 to 6000 cSt, 20 Weight percent dimer or less
and a viscosity index of 60 or more are obtained by contacting in a reaction Zone, in the …
and a viscosity index of 60 or more are obtained by contacting in a reaction Zone, in the …
Metallocene‐catalyzed propene/1‐hexene copolymerization: Influence of amount and bulkiness of cocatalyst and of solvent polarity
An investigation on the effect of the variation of the amount and the structure of cocatalyst
and of polarity of the solvent on propene/1‐hexene copolymerization with the isospecific …
and of polarity of the solvent on propene/1‐hexene copolymerization with the isospecific …
Effects of ethylene as comonomer on the active center distribution of 1-hexene polymerization with MgCl2-supported Ziegler–Natta catalysts
Z Fan, L Zhang, S Xia, Z Fu - Journal of Molecular Catalysis A: Chemical, 2011 - Elsevier
1-Hexene homopolymerization and 1-hexene–ethylene copolymerization with TiCl4/MgCl2–
Al (C2H5) 3 catalyst were compared to investigate the effect of ethylene on the distribution of …
Al (C2H5) 3 catalyst were compared to investigate the effect of ethylene on the distribution of …
Mechanism of internal and external electron donor effects on propylene polymerization with MgCl2‐supported Ziegler–Natta catalyst: New evidences based on active …
Y Weng, B Jiang, Z Fu, Z Fan - Journal of Applied Polymer …, 2018 - Wiley Online Library
ABSTRACT Two TiCl4/Di/MgCl2 type supported Ziegler–Natta catalysts were prepared by
loading dibutylphthalate or dicyclopentyldimethoxysilane (DCPDMS)(internal donor, Di) and …
loading dibutylphthalate or dicyclopentyldimethoxysilane (DCPDMS)(internal donor, Di) and …