Metal-containing clusters have attracted increasing attention over the past 2–3 decades.
This intense interest can be attributed to the fact that these discrete metal aggregates, whose …

Polyoxometalates are clusters of metal-oxide units, comprising a large diversity of nanoscale
structures, and have many common building blocks; in fact polyoxometalate clusters are …

Uranium-containing polyoxometalates (U-POMs), an important class of actinide cluster
compounds, are the products of the assembly of uranium or uranium and POMs. These …

Searching for suitable methods to construct all-inorganic cage materials by using
polyoxometalates (POMs) as secondary building units (SBUs) has been of great interest …

Metal oxide clusters, especially transition-metal polyoxometalates, have been studied for
decades because they provide a rare opportunity to study nanoscale materials with well …

Uranyl peroxide clusters containing from 16 to 124 uranyl ions self-assemble in aqueous
solution and exhibit tremendous topological complexity. Most of these clusters are cages …

The prevalent π–π interactions in 2D covalent organic frameworks (COFs) impart a certain
flexibility to the structures, making the stacking of COF layers susceptible to external stimuli …

The chemistry of the uranyl ion ([UO2] 2+) has evolved remarkably over the past few years,
with unexpected reactivity observed that challenge our understanding of this ion, and of …

By controlling the water content, a new poly-oxo-metalate species containing 38 uranium
centers has been solvothermally synthesized in the presence of benzoic acid in …

Room temperature calorimetry methods were developed to describe the energy landscapes
of six polyoxometalates (POMs), Li–U24, Li–U28, K–U28, Li/K–U60, Mo132, and Mo154, in …