3d− 4f combined chemistry: synthetic strategies and magnetic properties

M Andruh, JP Costes, C Diaz, S Gao - Inorganic chemistry, 2009 - ACS Publications
Heterometallic 3d− 4f complexes are of high interest in molecular magnetism: the lanthanide
ions bring large and, in most cases, anisotropic magnetic moments. The combination of 3d …

Heterometallic CuII–LnIII complexes: Single molecule magnets and magnetic refrigerants

A Dey, P Bag, P Kalita, V Chandrasekhar - Coordination Chemistry …, 2021 - Elsevier
Molecular nanomagnets containing heterometallic 3d-4f complexes have been investigated
extensively for the past few years realizing the role of exchange interaction to minimize the …

Relaxation dynamics of dysprosium (III) single molecule magnets

YN Guo, GF Xu, Y Guo, J Tang - Dalton Transactions, 2011 - pubs.rsc.org
Over the past decade, lanthanide compounds have become of increasing interest in the field
of Single Molecule Magnets (SMMs) due to the large inherent anisotropy of the metal ions …

Controlled association of single-molecule magnets (SMMs) into coordination networks: towards a new generation of magnetic materials

IR Jeon, R Clérac - Dalton transactions, 2012 - pubs.rsc.org
The field of molecular magnetism has rapidly expanded since the discovery of single-
molecule magnets (SMMs) at the beginning of the 1990s. Numerous SMMs have been …

Synthesis, Structure, and Magnetism of Heterobimetallic Trinuclear Complexes {[L2Co2Ln][X]} [Ln = Eu, X = Cl; Ln = Tb, Dy, Ho, X = NO3; LH3 = (S)P[N(Me)NCH−C6H3-2 …

V Chandrasekhar, BM Pandian, JJ Vittal… - Inorganic …, 2009 - ACS Publications
Sequential reaction of LH3 (LH3=(S) P [N (Me) N CH− C6H3-2-OH-3-OMe] 3) with Co
(OAc) 2· 4H2O followed by reaction with lanthanide salts afforded trinuclear heterobimetalllic …

{ScnGdn} Heterometallic Rings: Tunable Ring Topology for Spin-Wave Excitations

HL Zhang, YQ Zhai, H Nojiri, C Schröder… - Journal of the …, 2022 - ACS Publications
Data carriers using spin waves in spintronic and magnonic logic devices offer operation at
low power consumption and free of Joule heating yet requiring noncollinear spin structures …

Exchange coupling in TbCu and DyCu single-molecule magnets and related lanthanide and vanadium analogs

T Ishida, R Watanabe, K Fujiwara, A Okazawa… - Dalton …, 2012 - pubs.rsc.org
Heterometallic coordination compounds [CuII (L)(C3H6O) LnIII (NO3) 3] and [VIVO
(L)(C3H6O) LnIII (NO3) 3](abbreviated as LnCu and LnV, respectively; H2L= N, N′-bis (3 …

Probing the Origin of Ferro-/Antiferromagnetic Exchange Interactions in Cu (II)–4f Complexes

N Ahmed, T Sharma, L Spillecke, C Koo… - Inorganic …, 2022 - ACS Publications
The mechanistic investigations between Cu (II) and the anisotropic lanthanides (Ln (III)) are
not much explored to date. This is due to the complicated energy spectrum which arises due …

Pentanuclear 3d–4f Heterometal Complexes of MII3LnIII2 (M = Ni, Cu, Zn and Ln = Nd, Gd, Tb) Combinations: Syntheses, Structures, Magnetism, and …

M Maity, MC Majee, S Kundu, SK Samanta… - Inorganic …, 2015 - ACS Publications
A new family of pentanuclear 3d–4f heterometal complexes of general composition [LnIII2
(MIIL) 3 (μ3-O) 3H](ClO4)· x H2O (1–5)[Ln= Nd, M= Zn, 1; Nd, Ni, 2; Nd, Cu, 3; Gd, Cu, 4; Tb …

Strong Ferromagnetic Exchange Interactions in Hinge-like Dy(O2Cu)2 Complexes Involving Double Oxygen Bridges

Y Ida, S Ghosh, A Ghosh, H Nojiri, T Ishida - Inorganic Chemistry, 2015 - ACS Publications
Two trinuclear isomeric compounds,[{(CuII (salpn))(Me (CO) Me)} 2DyIII (NO3) 3](1) and
[{CuII (salpn)} 2DyIII (H2O)(NO3) 3]· MeOH (2), along with one polymeric compound,{[{CuII …