Recent advances in the catalytic N-methylation and N-trideuteromethylation reactions using methanol and deuterated methanol

V Goyal, N Sarki, A Narani, G Naik, K Natte… - Coordination Chemistry …, 2023 - Elsevier
N-methylamine functionalities are valuable motifs, which play vital roles in the properties
and activities of essential fine and bulk chemicals including molecules used in life science …

Methanol as a greener C1 synthon under non-noble transition metal-catalyzed conditions

P Mehara, P Das - Coordination Chemistry Reviews, 2023 - Elsevier
The exploration of methanol as a safe, easily accessible as well as environmentally benign
C1 synthon has captivated gigantic attention worldwide. It has surfaced as an increasingly …

Homogeneous Catalysis for the Conversion of CO2, CO, CH3OH, and CH4 to C2+ Chemicals via C–C Bond Formation

SA Fors, CA Malapit - ACS Catalysis, 2023 - ACS Publications
In the past few decades, the advances of CO2 reduction have been mostly focused on the
synthesis of C1 products, such as CO, formic acid, methanol, and methane. However, the …

Well-defined bis (NHC) Mn (I) complex catalyzed tandem transformation of α, β-unsaturated ketones to α-methylated ketones using methanol

K Ganguli, A Mandal, S Kundu - ACS Catalysis, 2022 - ACS Publications
Tandem transformation of α, β-unsaturated ketones to α-methylated ketones by utilizing
methanol as both the hydrogen and C1 sources is reported in the presence of a phosphine …

Alcohol-alcohol cross-coupling enabled by SH2 radical sorting

R Chen, NE Intermaggio, J Xie, JA Rossi-Ashton… - Science, 2024 - science.org
Alcohols represent a functional group class with unparalleled abundance and structural
diversity. In an era of chemical synthesis that prioritizes reducing time to target and …

Borrowing Hydrogen β-Phosphinomethylation of Alcohols Using Methanol as C1 Source by Pincer Manganese Complex

F Sun, X Chen, S Wang, F Sun… - Journal of the American …, 2023 - ACS Publications
Herein, we report a manganese-catalyzed three-component coupling of β-H containing
alcohols, methanol, and phosphines for the synthesis of γ-hydroxy phosphines via a …

Magnetic MoS 2 efficient heterogeneous photocatalyst for the α-methoxymethylation and aminomethylation of aromatic ketones

YM Wang, WJ Li, MM Wang, M Zhang… - Catalysis Science & …, 2023 - pubs.rsc.org
Magnetic MoS2 quantum dot (CuFeO2/polydopamine (PDA)/MoS2) was prepared through a
facile and convenient method. The structure and texture of the as-prepared catalyst were …

Iridium-, ruthenium-, and nickel-catalyzed C–C couplings of methanol, formaldehyde, and ethanol with π-unsaturated pronucleophiles via hydrogen transfer

CC Meyer, MJ Krische - The Journal of organic chemistry, 2022 - ACS Publications
In this Perspective, the use of methanol and ethanol as C1 and C2 feedstocks in metal-
catalyzed C–C couplings to π-unsaturated pronucleophiles via hydrogen auto-transfer is …

α-Methylation of Ketones and Indoles Catalyzed by a Manganese(I) PCNHCP Pincer Complex with Methanol as a C1 Source

R Thenarukandiyil, R Kamte, S Garhwal… - …, 2022 - ACS Publications
Acceptorless alcohol dehydrogenation is a powerful reaction in sustainable synthesis. When
combined in a tandem reaction with dehydrogenative coupling or hydrogen borrowing …

Pincer-Cobalt-Catalyzed Guerbet-Type β-Alkylation of Alcohols in Air under Microwave Conditions

PG Nandi, P Thombare, SJ Prathapa, A Kumar - Organometallics, 2022 - ACS Publications
Pincer complexes of the type (R2NNN) CoCl2 (R= i Pr, t Bu, Cy, Ph, pF-C6H4) derived from
the environmentally benign, earth-abundant, and inexpensive base metal cobalt have been …