Transition metal carbide complexes
A Reinholdt, J Bendix - Chemical Reviews, 2021 - ACS Publications
Carbide complexes remain a rare class of molecules. Their paucity does not reflect
exceptional instability but is rather due to the generally narrow scope of synthetic …
exceptional instability but is rather due to the generally narrow scope of synthetic …
Synthesis of the Highly Reduced [Fe6C(CO)15]4– Carbonyl Carbide Cluster and Its Reactions with H+ and [Au(PPh3)]+
M Bortoluzzi, I Ciabatti, C Cesari… - European Journal of …, 2017 - Wiley Online Library
The reduction of [Fe6C (CO) 16] 2–(1) with NaOH in DMSO or with Na/naphthalene in THF
affords the highly reduced [Fe6C (CO) 15] 4–(2) monocarbide tetraanion. The molecular …
affords the highly reduced [Fe6C (CO) 15] 4–(2) monocarbide tetraanion. The molecular …
Molecular nickel poly-carbide carbonyl nanoclusters: The octa-carbide [HNi42C8 (CO) 44 (CuCl)] 7–and the deca-carbide [Ni45C10 (CO) 46] 6–
A Bernardi, I Ciabatti, C Femoni, MC Iapalucci… - Journal of …, 2016 - Elsevier
The reaction of [Ni 10 (C 2)(CO) 16] 2–with CuCl in thf affords [Ni 45 C 10 (CO) 46] 6–as the
major product. This represents the first deca-carbide carbonyl cluster and this is the highest …
major product. This represents the first deca-carbide carbonyl cluster and this is the highest …
Peraurated nickel carbide carbonyl clusters: the cationic [Ni 6 (C)(CO) 8 (AuPPh 3) 8] 2+ monocarbide and the [Ni 12 (C)(C 2)(CO) 17 (AuPPh 3) 3]− anion containing …
M Bortoluzzi, I Ciabatti, C Femoni, M Hayatifar… - Dalton …, 2014 - pubs.rsc.org
Two new peraurated Ni-carbide carbonyl clusters have been prepared and structurally
characterized, ie [Ni6 (C)(CO) 8 (AuPPh3) 8] 2+ and [Ni12 (C)(C2)(CO) 17 (AuPPh3) 3] …
characterized, ie [Ni6 (C)(CO) 8 (AuPPh3) 8] 2+ and [Ni12 (C)(C2)(CO) 17 (AuPPh3) 3] …
Co5C and Co4C carbido carbonyl clusters stabilized by [AuPPh3]+ fragments
I Ciabatti, C Femoni, M Hayatifar, MC Iapalucci… - Inorganica Chimica …, 2015 - Elsevier
The synthesis and structural characterization of [Co 5 C (CO) 11 (AuPPh 3) 3], 1-A and 1-
B,[Co 5 C (CO) 11 (AuPPh 3) 2]−, 2,[Co 5 C (CO) 10 (PPh 3) 2 (AuPPh 3)], 3,[Co 5 C (CO) 12 …
B,[Co 5 C (CO) 11 (AuPPh 3) 2]−, 2,[Co 5 C (CO) 10 (PPh 3) 2 (AuPPh 3)], 3,[Co 5 C (CO) 12 …
Structural variations, electrochemical properties and computational studies on monomeric and dimeric Fe–Cu carbide clusters, forming copper-based staple arrays
The halide ligands of [Fe4C (CO) 12 (CuCl) 2] 2−(1) and [Fe5C (CO) 14CuCl] 2−(2) can be
displaced by N-, P-or S-donors. Beside substitution, the clusters easily undergo structural …
displaced by N-, P-or S-donors. Beside substitution, the clusters easily undergo structural …
Synthesis and Characterization of Heteromultinuclear Ni/M Clusters (M = Fe, Ru, W) Including a Paramagnetic (NHC)Ni–WCp*(CO)3 Heterobinuclear Complex
A diverse range of heteromultinuclear NiI/[MCO] clusters (MCO= CpFe (CO) 2, CpRu (CO) 2,
Cp* W (CO) 3) supported by an N-heterocyclic carbene ligand have been synthesized by …
Cp* W (CO) 3) supported by an N-heterocyclic carbene ligand have been synthesized by …
Synthesis and Structural Characterization of Bimetallic Iron− Nickel Carbido Cluster Complexes
In acetonitrile solvent, Fe5 (CO) 15 (μ5-C), 1, reacts with Ni (COD) 2 at room temperature to
afford the iron− nickel complex Fe5Ni (NCMe)(CO) 15 (μ6-C), 3. The acetonitrile ligand in 3 …
afford the iron− nickel complex Fe5Ni (NCMe)(CO) 15 (μ6-C), 3. The acetonitrile ligand in 3 …
Capping [H8−nNi42C8(CO)44]n− (n = 6, 7, 8) Octa-carbide Carbonyl Nanoclusters with [Ni(CO)] and [CuCl] Fragments
C Cesari, I Ciabatti, C Femoni, MC Iapalucci… - Journal of Cluster …, 2017 - Springer
The reactions of [Ni 16 (C 2) 2 (CO) 23] 4− and [Ni 38 C 6 (CO) 42] 6− with CuCl afforded
mixtures of the previously reported [HNi 42 C 8 (CO) 44 (CuCl)] 7− bimetallic octa-carbide …
mixtures of the previously reported [HNi 42 C 8 (CO) 44 (CuCl)] 7− bimetallic octa-carbide …
The redox chemistry of [Ni9C (CO) 17] 2–and [Ni10 (C2)(CO) 16] 2–: Synthesis, electrochemistry and structure of [Ni12C (CO) 18] 4–and [Ni22 (C2) 4 (CO) 28 (Et2S)] 2 …
I Ciabatti, C Femoni, T Funaioli, MC Iapalucci… - Journal of …, 2017 - Elsevier
This paper reports a detailed study of the oxidation and reduction reactions of simple nickel
mono-carbide and mono-acetlyde carbonyl clusters. The reduction of [Ni 9 C (CO) 17] 2 …
mono-carbide and mono-acetlyde carbonyl clusters. The reduction of [Ni 9 C (CO) 17] 2 …