Assembly of air-stable copper (I) alkynide nanoclusters assisted by tripodal polydentate phosphoramide ligands

H Zhao, C Zhang, B Han, Z Wang, Y Liu, Q Xue… - Nature …, 2024 - nature.com
Copper (I) nanoclusters are attractive due to their potential applications, but their synthesis
remains challenging due to susceptibility to oxidation and the lack of mature synthetic …

Polyanionic Imido‐P (V) Ligands: From Transition Metal Complexes to Coordination Driven Self‐Assemblies

M Sarkar, P Rajasekar, C Jose… - The Chemical …, 2022 - Wiley Online Library
The chemistry of the imido‐anions of the main group elements has been studied for more
than three decades. The imido (NR)− group is isoelectronic to the oxo (= O) group and can …

Unraveling Ultralong Phosphorescence in Ar2PO(H): n(O) → σ*(PC) Transitions in Ar2PO(H) Stabilize Triplet States Better than n(P) → σ*(PC) in Ar3P

S Jena, AT Muhammed Munthasir… - The Journal of Physical …, 2023 - ACS Publications
Herein, we report the crystallization-induced persistent room-temperature phosphorescence
(CIpRTP) characteristics of simple diarylphosphine oxides 1, 2, and 3. Under ambient …

Database analysis of hydrogen bond patterns in phosphoric triamides completed with seven new compounds: a crystallographic and 15 N NMR study

M Pourayoubi, M Toghraee, J Zhu, M Dušek… - …, 2014 - pubs.rsc.org
We present the synthesis and characterization of seven new phosphoric triamides followed
by analysis of hydrogen bond patterns of the new compounds as well as the phosphoric …

A novel silver (I) two-dimensional coordination polymer of thiophosphoric triamide ligand with two different coordination modes: Experimental, theoretical and …

Z Gholamrezaei, A Tarahhomi - Journal of Molecular Structure, 2025 - Elsevier
Novel thiophosphoric triamide (S) P [NC 4 H 8 O] 3 (PS, compound 1) and silver (I) two-
dimensional coordination polymer derived from it ([Ag (I) 3 (PS) 2 (NO 3) 3] n, 2) as the first …

Facile formation of stable tris (imido) phosphate trianions as their tri-and hexanuclear Pd (II) complexes in protic solvents

AK Gupta, SAD Reddy, R Boomishankar - Inorganic Chemistry, 2013 - ACS Publications
Employing Pd (OAc) 2, a facile deprotonation route to access the highly basic tris
(alkylimido) phosphate trianions,[(RN) 3PO] 3–(R= tBu, cHex, or iPr), analogous to the …

Zn (ii) coordination polymer of an in situ generated 4-pyridyl (4 Py) attached bis (amido) phosphate ligand,[PO 2 (NH 4 Py) 2]− showing preferential water uptake over …

AK Gupta, SS Nagarkar, R Boomishankar - Dalton Transactions, 2013 - pubs.rsc.org
Two polymorphic 2D-coordination polymers of composition [ZnL (HCO2)]∞ were
synthesized from an in situ generated ligand [PO2 (NH4Py) 2]−(L−). The ligand L− was …

Experimental and theoretical study of novel amino‐functionalized P(V) coordination compounds suggested as inhibitor of MPro of SARS‐COV‐2 by molecular …

M Najarianzadeh, A Tarahhomi… - Applied …, 2022 - Wiley Online Library
Amino‐functionalized P (V) derivatives providing both N‐and O‐donor modes have attracted
interest owing to their potential to form interesting coordination assemblies with applications …

Discrete and Polymeric Cu(II) Complexes Derived from in Situ Generated Pyridyl-Functionalized Bis(amido)phosphate Ligands, [PO2(NHPy)2]

AK Gupta, AK Srivastava, IK Mahawar… - Crystal growth & …, 2014 - ACS Publications
New examples of Cu (II) complexes containing in situ generated bis (amido) phosphate
ligands,[PO2 (NHPy) 2]−, have been synthesized [(L1)−, where Py= 2-pyridyl, and (L2) …

Coordination versus hydrogen bonds in the structures of different tris (pyridin-2-yl) phosphoric triamide derivatives

M Sebghati, A Tarahhomi, MS Bozorgvar… - RSC …, 2021 - pubs.rsc.org
The crystalline forms of tris (pyridin-2-yl) phosphoric triamide, OP [NH-2Py] 3 were
investigated using single crystal X-ray diffraction, both as a metal complex [Co {(O) P [NH …