Carbonyl and olefin adducts of coinage metals supported by poly (pyrazolyl) borate and poly (pyrazolyl) alkane ligands and silver mediated atom transfer reactions

HVR Dias, CJ Lovely - Chemical reviews, 2008 - ACS Publications
Tris (pyrazolyl) borates, first reported about 40 years ago, are a very useful class of
monoanionic, nitrogen-based, auxiliary ligands in coordination and organometallic and …

Binding and activation of nitrite and nitric oxide by copper nitrite reductase and corresponding model complexes

AC Merkle, N Lehnert - Dalton Transactions, 2012 - pubs.rsc.org
The reduction of nitrite to nitric oxide in dissimilatory denitrification is carried out by copper
nitrite reductases (CuNIRs) via a type 2 copper site. Extended studies on CuNIRs in …

Reversible Metalation and Catalysis with a Scorpionate-like Metallo-ligand in a Metal–Organic Framework

C Sun, G Skorupskii, JH Dou, AM Wright… - Journal of the …, 2018 - ACS Publications
The installation of metallo-ligands in metal–organic frameworks (MOFs) is an effective
means to create site-isolated metal centers toward single-site heterogeneous catalysis …

Synthesis and spectroscopic characterization of copper (II)− nitrito complexes with hydrotris (pyrazolyl) borate and related coligands

N Lehnert, U Cornelissen, F Neese, T Ono… - Inorganic …, 2007 - ACS Publications
This study focuses on the geometric (molecular) structures, spectroscopic properties, and
electronic structures of copper (II)− nitrito complexes as a function of second coordination …

Trispyrazolylborate coinage metals complexes: Structural features and catalytic transformations

JM Muñoz-Molina, TR Belderrain, PJ Pérez - Coordination Chemistry …, 2019 - Elsevier
Tris (pyrazolyl) borates (Tp x) have become one of the most broadly used polydentate
anionic ligands in coordination chemistry and catalysis since Trofimenko introduced them in …

Structure and bonding in copper (I) carbonyl and cyanide complexes

RD Pike - Organometallics, 2012 - ACS Publications
The coordination chemistry of copper (I) carbonyls and cyano complexes is reviewed.
Primary attention is focused on structural chemistry, including coordination behavior …

Synthesis and Reaction of [(TpiPr2)LnH2]3 (Ln = Y, Lu) with CO: Trinuclear Cluster-Bound Propenolate en Route to Selective Formation of Propene

J Cheng, MJ Ferguson, J Takats - Journal of the American …, 2010 - ACS Publications
The use of the Tp i Pr2 ligand led to the straightforward and high-yield synthesis of rare
examples of trinuclear monoligand lanthanide dihydrides,[(Tp i Pr2) LnH2] 3 (Ln= Y, Lu) …

Efficient biomimetic hydroxylation catalysis with a bis (pyrazolyl) imidazolylmethane copper peroxide complex

C Wilfer, P Liebhäuser, A Hoffmann… - … A European Journal, 2015 - Wiley Online Library
Bis (pyrazolyl) methane ligands are excellent components of model complexes used to
investigate the activity of the enzyme tyrosinase. Combining the N donors 3‐tert …

Classical Gold Carbonyl Complexes in Tetrahedral and Trigonal‐Planar Settings

M Vanga, A Muñoz‐Castro… - Chemistry–A European …, 2024 - Wiley Online Library
A unique four‐coordinate, classical gold (I)‐carbonyl complex with substantial backdonation
from gold has been isolated by using a B‐methylated and fluorinated tris (pyridyl) borate …

Structural and spectroscopic characterization of mononuclear copper (I) nitrosyl complexes: end-on versus side-on coordination of NO to copper (I)

K Fujisawa, A Tateda, Y Miyashita… - Journal of the …, 2008 - ACS Publications
Two crystal structures of the mononuclear copper (I)− nitrosyl complexes [Cu (L3)(NO)](1)
and [Cu (L3 ')(NO)](ClO4)(2) with the related coligands L3-(hydrotris (3-tert-butyl-5-isopropyl …