Reactions in single-molecule junctions

H Chen, C Jia, X Zhu, C Yang, X Guo… - Nature Reviews …, 2023 - nature.com
Developing new materials is a long-standing goal that extends across the fields of synthesis,
catalysis, nanotechnology and materials science. Transforming one compound or material …

Structure and reactivity/selectivity control by oriented-external electric fields

S Shaik, R Ramanan, D Danovich… - Chemical Society …, 2018 - pubs.rsc.org
This is a tutorial on use of external-electric-fields (EEFs) as effectors of chemical change.
The tutorial instructs readers how to conceptualize and design electric-field effects on bonds …

Electric-field mediated chemistry: uncovering and exploiting the potential of (oriented) electric fields to exert chemical catalysis and reaction control

S Shaik, D Danovich, J Joy, Z Wang… - Journal of the American …, 2020 - ACS Publications
This Perspective discusses oriented external-electric-fields (OEEF), and other electric-field
types, as “smart reagents”, which enable in principle control over wide-ranging aspects of …

Electric fields in catalysis: From enzymes to molecular catalysts

NG Léonard, R Dhaoui, T Chantarojsiri, JY Yang - ACS catalysis, 2021 - ACS Publications
Electric fields underlie all reactions and impact reactivity by interacting with the dipoles and
net charges of transition states, products, and reactants to modify the free energy landscape …

Oriented electric fields as future smart reagents in chemistry

S Shaik, D Mandal, R Ramanan - Nature chemistry, 2016 - nature.com
Oriented external electric fields (OEEFs) as' smart reagents' are no longer a theoretical
dream. Here, we discuss the wide-ranging potential of using OEEFs to catalyse and control …

High electric fields on water microdroplets catalyze spontaneous and fast reactions in halogen-bond complexes

C Zhu, LN Pham, X Yuan, H Ouyang… - Journal of the …, 2023 - ACS Publications
The use of external electric fields as green and efficient catalysts in synthetic chemistry has
recently received significant attention for their ability to deliver remarkable control of reaction …

Harnessing electrostatic catalysis in single molecule, electrochemical and chemical systems: a rapidly growing experimental tool box

S Ciampi, N Darwish, HM Aitken, I Díez-Pérez… - Chemical Society …, 2018 - pubs.rsc.org
Static electricity is central to many day-to-day practical technologies, from separation
methods in the recycling of plastics to transfer inks in photocopying, but the exploration of …

Elucidating the roles of electric fields in catalysis: a perspective

F Che, JT Gray, S Ha, N Kruse, SL Scott… - ACS …, 2018 - ACS Publications
This Perspective illustrates how the presence of internal and external electric fields can
affect catalytic activity and selectivity, with a focus on heterogeneous catalysts. Specifically …

Adsorbed cobalt porphyrins act like metal surfaces in electrocatalysis

CJ Kaminsky, S Weng, J Wright, Y Surendranath - Nature Catalysis, 2022 - nature.com
Electrodes chemically modified with molecular active sites are potent catalysts for energy
conversion reactions. Such electrodes are typically presumed to operate by the same redox …

Harnessing the high interfacial electric fields on water microdroplets to accelerate Menshutkin reactions

Z Song, C Liang, K Gong, S Zhao, X Yuan… - Journal of the …, 2023 - ACS Publications
Even though it is still an emerging field, the application of a high external electric field (EEF)
as a green and efficient catalyst in synthetic chemistry has recently received significant …