Selected developments and medical applications of organic–inorganic hybrid biomaterials based on functionalized spherosilicates

Ł John - Materials Science and Engineering: C, 2018 - Elsevier
Well-defined and tailor-made spherosilicates and POSS-based (POSS= Polyhedral
Oligomeric Silsesquioxanes)(nano) composites with interesting chemical and mechanical …

Are Well Performing Catalysts for the Ring Opening Polymerization of l-Lactide under Mild Laboratory Conditions Suitable for the Industrial Process? The Case of …

MC D'Alterio, I D'Auria, L Gaeta, C Tedesco… - …, 2022 - ACS Publications
Poly (lactic acid)(PLA) is one of the best candidates as a sustainable plastic material for a
circular economy, being biodegradable, bio-based, recyclable, and displaying good thermal …

Mono-BHT heteroleptic magnesium complexes: Synthesis, molecular structure and catalytic behavior in the ring-opening polymerization of cyclic esters

IE Nifant'Ev, AV Shlyakhtin, VV Bagrov… - Dalton …, 2017 - pubs.rsc.org
Numerous heteroleptic 2, 6-di-tert-butyl-4-methylphenolate (BHT) magnesium complexes
have been synthesized by treatment of (BHT) MgBu (THF) 2 with various alcohols. Molecular …

Bio-and chemocatalysis cascades as a bridge between biology and chemistry for green polymer synthesis

A Marszałek-Harych, D Jędrzkiewicz, J Ejfler - Cellular & Molecular Biology …, 2017 - Springer
The development and integration of bio-and chemocatalytic processes to convert renewable
or biomass feedstocks into polymers is a vibrant field of research with enormous potential for …

Lactide as the playmaker of the ROP game: theoretical and experimental investigation of ring-opening polymerization of lactide initiated by aminonaphtholate zinc …

D Jedrzkiewicz, G Adamus, M Kwiecień… - Inorganic …, 2017 - ACS Publications
A family of homo-and heteroleptic zinc complexes bearing aminonaphtholate ligands was
synthesized and fully characterized. Using NMR spectroscopy and DFT calculation, bis …

Zinc 8-aminotrihydroquinolines appended with pendant N-diphenylphosphinoethyl arms as exceptionally active catalysts for the ROP of ε-CL

F Cao, Y Wang, X Wang, W Zhang, GA Solan… - Catalysis Science & …, 2022 - pubs.rsc.org
Five types of N-(2-(diphenylphosphino) ethyl)-2-R-5, 6, 7, 8-tetrahydroquinolin-8-amines (R=
H L1, Me L2, iPr L3, Cl L4, Ph L5) along with one example of an N-isopropyl-5, 6, 7, 8 …

Sodium complexes as precise tools for cutting polymer chains. Exploration of PLA degradation by unique cooperation of sodium centers

E Nizioł, D Jędrzkiewicz, A Wiencierz, W Paś… - Inorganic Chemistry …, 2023 - pubs.rsc.org
Novel sodium coordination compounds with aminonaphtholate and aminophenolate ligands
have been synthesized and characterized by spectroscopic methods, X-ray analysis, and …

Toward the Synthesis of Heteroleptic Zinc ROP Initiators Based on Pyridine-Containing Monoalcohols by Tuning Ligand Substituents

EA Kuchuk, BN Mankaev, KV Zaitsev… - …, 2023 - ACS Publications
Synthesis of two types of complexes (heteroleptic vs homoleptic) is accomplished by an
elegant variation of the ligand design. Heteroleptic ethyl zinc complexes 1a–3a were cleanly …

N-Activated 1, 3-Benzoxazine Monomer as a Key Agent in Polybenzoxazine Synthesis

D Trybuła, A Marszałek-Harych, M Gazińska… - …, 2020 - ACS Publications
A novel and successful application of ring-closing reactions of aminophenols has been
proposed for the formation of a new type of 1, 3-benzoxazine ionic derivatives. The …

Ring-opening polymerization of ε-caprolactone and L-lactide using ethyl salicylate-bearing zinc complexes as catalysts

RR Su, PK Ganta, CA Cheng, YT Hu, YC Chang… - Molecular …, 2023 - Elsevier
A series of zinc complexes bearing ethyl salicylates were synthesized, and their catalytic
activity in the polymerization of ε-caprolactone (CL) and l-lactide (LA) was investigated. In …