Flexible porous frameworks are at the forefront of materials research. A unique feature is
their ability to open and close their pores in an adaptive manner induced by chemical and …

Since the first pioneering studies on small deuterated peptides dating more than 20 years
ago, 1H detection has evolved into the most efficient approach for investigation of …

Ni-rich layered cathode materials are among the most promising candidates for high-energy-
density Li-ion batteries, yet their degradation mechanisms are still poorly understood. We …

Paramagnetic chemical probes have been used in electron paramagnetic resonance (EPR)
and nuclear magnetic resonance (NMR) spectroscopy for more than four decades. Recent …

Electrochemical ion insertion involves coupled ion–electron transfer reactions, transport of
guest species and redox of the host. The hosts are typically anisotropic solids with 2D …

Solid-state magic-angle spinning NMR spectroscopy is a powerful technique to probe
atomic-level microstructure and structural dynamics in metal halide perovskites. It can be …

Solid-state nuclear magnetic resonance (NMR) spectroscopy is an atomic-level method to
determine the chemical structure, 3D structure and dynamics of solids and semi-solids. This …

Chemical shifts present crucial information about an NMR spectrum. They show the
influence of the chemical environment on the nuclei being probed. Relativistic effects …

Graphite is the most commercially successful anode material for lithium (Li)-ion batteries: its
low cost, low toxicity, and high abundance make it ideally suited for use in batteries for …

Paramagnetic centers in biomolecules, such as specific metal ions that are bound to a
protein, affect the nuclei in their surrounding in various ways. One of these effects is the …