Strecker reaction and α-amino nitriles: Recent advances in their chemistry, synthesis, and biological properties

VV Kouznetsov, CEP Galvis - Tetrahedron, 2018 - Elsevier
Abstract α-Amino nitrile compounds have a profound impact on bio-chemical sciences, as
they have been prepared from inexpensive starting materials and have become valuable …

An overview on the progress and development on metals/non-metal catalyzed cyanation reactions

T Najam, SSA Shah, K Mehmood, AU Din… - Inorganica Chimica …, 2018 - Elsevier
This review is based on the analysis of recent developments on cyanation reactions for the
synthesis of nitriles (RCN) through transition metal mediated cyanation reaction as well as …

Potassium thiocyanate as source of cyanide for the oxidative α-cyanation of tertiary amines

A Wagner, AR Ofial - The Journal of Organic Chemistry, 2015 - ACS Publications
Oxidation at the sulfur of the safe-to-handle potassium thiocyanate releases cyanide units
that are trapped in the presence of co-oxidized tertiary amines to form α-amino nitriles …

Template-free, facile synthesis of nickel promoted multi-walled MoS2 & nano-bricks containing hierarchical MoS2 nanotubes from the bulk NiMo oxide

RK Chowdari, JND de León… - Applied Catalysis B …, 2021 - Elsevier
A low-temperature and template-free synthesis method was developed to prepare MoS 2
nanotubes by sulfidation of bulk NiMo oxide. The ex-situ gas-phase low-pressure sulfidation …

α‐Cyanation of aromatic tertiary amines using ferricyanide as a Non‐Toxic cyanide source

AM Nauth, N Otto, T Opatz - Advanced Synthesis & Catalysis, 2015 - Wiley Online Library
The reaction of aromatic tertiary amines with potassium ferricyanide directly provides the
useful α‐amino nitriles. The inexpensive iron complex functions both as an oxidant and as a …

Direct oxidative cyanation of tertiary amines promoted by in situ generated hypervalent iodine (III)-CN intermediate

H Shen, X Zhang, Q Liu, J Pan, W Hu, Y Xiong, X Zhu - Tetrahedron Letters, 2015 - Elsevier
An environmentally benign and metal-free cyanation method of tertiary amines oxidated by
hypervalent iodine (III) intermediate generated in situ from PIFA (or DIB) and TMSCN has …

Heteropoly acid catalysts in upgrading of biorenewables: Synthesis of para-menthenic fragrance compounds from α-pinene oxide

CJA Ribeiro, MM Pereira, EF Kozhevnikova… - Catalysis Today, 2020 - Elsevier
The isomerization of α-pinene oxide in the presence of Cs 2.5 H 0.5 PW 12 O 40 (CsPW)
heteropolysalt as solid acid catalyst is reported. The reactions were performed in various …

Mild and highly efficient metal-free oxidative α-cyanation of N-acyl/sulfonyl tetrahydroisoquinolines

C Yan, Y Liu, Q Wang - RSC advances, 2014 - pubs.rsc.org
A highly efficient metal-free oxidative α-cyanation reaction of N-acyl/sulfonyl
tetrahydroisoquinolines under mild conditions was developed. The reaction uses 2, 2, 6, 6 …

Iron-catalysed sequential reaction towards α-aminonitriles from secondary amines, primary alcohols and trimethylsilyl cyanide

H Shen, L Hu, Q Liu, MI Hussain, J Pan… - Chemical …, 2016 - pubs.rsc.org
Iron-catalysed sequential reaction towards α-aminonitriles from secondary amines, primary
alcohols and trimethylsilyl cyanide - Chemical Communications (RSC Publishing) DOI:10.1039/C5CC10346K …

Metal-free aerobic oxidative cyanation of tertiary amines: azobis (isobutyronitrile)(AIBN) as a sole cyanide source

PY Liu, C Zhang, SC Zhao, F Yu, F Li… - The Journal of Organic …, 2017 - ACS Publications
An aerobic oxidative cyanation for the synthesis of α-aminonitriles was reported. The
formation of C (sp3)-CN bonds was achieved under a metal-free condition by utilizing azobis …