Nanoporous molecular crystals

NB McKeown - Journal of Materials Chemistry, 2010 - pubs.rsc.org
Nanoporous Molecular Crystals (NMCs) are nanoporous materials composed of discrete
molecules between which there are only non-covalent interactions—ie they do not possess …

Zinc (II) and cadmium (II) complexes with 1, 3, 5-benzenetricarboxylate and imidazole-containing ligands: structural variation via reaction temperature and solvent

L Luo, K Chen, Q Liu, Y Lu, T Okamura… - Crystal growth & …, 2013 - ACS Publications
Five new metal complexes,[Zn3 (L1) 2 (BTC) 2]· 6H2O (1),[Zn3 (L1)(BTC) 2](2),[Cd3
(L1)(BTC) 2](3),[Cd3 (L2)(BTC) 2]· 4H2O (4), and [Cd3 (L2)(BTC) 2 (H2O) 2](5), have been …

Effect of coordinated solvent molecules on metal coordination sphere and solvent-induced transformations

WQ Zhang, WY Zhang, RD Wang, CY Ren… - Crystal Growth & …, 2017 - ACS Publications
Four similar Mn (II) metal–organic frameworks (MOFs),{[Mn2 (nbtc)(H2O) 2 (S)]· S· 0.5 H2O}
n [S= DMF (1), DMA (2), NMP (3), DEF (4)](DMF= N, N′-dimethylformamide, DMA= N, N …

Exceptional Crystallization Diversity and Solid‐State Conversions of CdII Coordination Frameworks with 5‐Bromonicotinate Directed by Solvent Media

CP Li, JM Wu, M Du - Chemistry–A European Journal, 2012 - Wiley Online Library
A series of nine coordination polymers {[Cd (L) 2 (solvent) x](solvent) y} n have been
prepared from Cd (NO3) 2 and 5‐bromonicotinic acid (HL) in different solvents through a …

Temperature-dependent in situ reduction of 4, 4′-azobispyridine via solvothermal reaction

YL Gai, FL Jiang, KC Xiong, L Chen… - Crystal growth & …, 2012 - ACS Publications
Solvothermal reactions of 2, 2′-biphenyldicarboxylate (H2dpa) and 4, 4′-azobispyridine
(azpy) in the presence of transition metal ions produce six new complexes, namely,[Co …

Temperature-driven assembly of Ln (III)(Ln= Nd, Eu, Yb) coordination polymers of a flexible azo calix [4] arene polycarboxylate ligand

LL Liu, ZG Ren, LW Zhu, HF Wang, WY Yan… - Crystal growth & …, 2011 - ACS Publications
Solvothermal reactions of LnCl3· 6H2O (Ln= Nd, Eu, Yb) with equimolar amounts of 5, 11,
17, 23-tetrakis [(m-carboxyphenyl) azo]-25, 26, 27, 28-tetrahydroxycalix [4] arene (H4L) at 90 …

Metal-directed assembly of coordination polymers with the versatile ligand 2-(1 H-benzotriazol-1-yl) acetic acid: from discrete structures to two-dimensional networks

JH Wang, GM Tang, YT Wang, TX Qin, SW Ng - CrystEngComm, 2014 - pubs.rsc.org
Eight new metal coordination complexes, namely,[Co (BTA) 2 (H2O) 4]· 6H2O (1),[Ni (BTA) 2
(H2O) 4]· 6H2O (2),[Cu2 (HBTA) 4 (BTA) 2]· 2H2O (3),[Ag (BTA)(H2O)] n (4),[Zn (BTA) 2 …

Temperature controlling polymorphism and polymorphic interconversion in sublimation crystallization of 5-methoxy-salicylaldhyde azine

S Shen, G Xia, Z Jiang, Q Shao, W Shan… - Crystal Growth & …, 2018 - ACS Publications
Traditional growth of organic crystals is mostly based on solution processing techniques, but
facile crystal preparation of compounds with poor solubility or polymorphic characters …

Solvent and guest-driven supramolecular organic frameworks based on a calix [4] arene-tetrol: channels vs molecular cavities

N Hickey, V Iuliano, C Talotta, M De Rosa… - Crystal Growth & …, 2021 - ACS Publications
Cone-shaped calix [4] arene-tetrol 3 has the ability to form open structures due to the
presence of four OH groups at the upper rim, which allows the construction of H-bonded …

Five MOFs with different topologies based on anthracene functionalized tetracarboxylic acid: syntheses, structures, and properties

F Liu, L Zhang, R Wang, J Sun, J Yang, Z Chen… - …, 2014 - pubs.rsc.org
Five coordination polymers based on 5, 5′-(2, 3, 6, 7-tetramethoxyanthracene-9, 10-diyl)
diisophthalic acid (H4LOMe):[Mn4 (LOMe)(OAc) 2 (μ3-OH) 2 (NMP) 4 (H2O) 2]· 2H2O …