Synergistic catalysis, a type of plural catalysis which utilizes at least two different catalysts to
enable a reaction between two separately activated substrates, has unlocked a plethora of …

The use of two or more metal catalysts in a reaction is a powerful synthetic strategy to access
complex targets efficiently and selectively from simple starting materials. While capable of …

From its beginnings in the Sonogashira reaction, synergistic dual transition-metal catalysis
has gained increasing prominence and importance. In the past decade, this strategy has …

We report the incorporation of large substituents based on heavy main-group elements that
are atypical in ligand architectures to enhance dispersion interactions and, thereby …

Olefins are synthetically useful building blocks in modern organic synthesis. Direct
functionalization of olefins; represent one of the most explored transformations in synthetic …

Factors controlling the regioselectivity in alkene hydrocupration were computationally
investigated using energy decomposition analysis. The results demonstrate that the …

Complementary to the design of a single structurally complex chiral ligand to promote each
step in transition‐metal catalysis, multiligand relay catalysis through dynamic ligand …

Abstract α‐Stereogenic allyl metalloids are versatile synthetic intermediates which can
undergo various stereocontrolled transformations. Most existing methods to prepare α …

The catalytic enantioselective synthesis of α-chiral olefins represents a valuable strategy for
rapid generation of structural diversity in divergent syntheses of complex targets. Herein, we …

The asymmetric hydroaminocarbonylation of olefins represents a straightforward approach
for the synthesis of enantioenriched amides, but is hampered by the necessity to employ CO …