Desulfonylation via radical process: recent developments in organic synthesis

XQ Chu, D Ge, YY Cui, ZL Shen, CJ Li - Chemical reviews, 2021 - ACS Publications
As the “chemical chameleon”, sulfonyl-containing compounds and their variants have been
merged with various types of reactions for the efficient construction of diverse molecular …

Greener synthesis of chemical compounds and materials

OV Kharissova, BI Kharisov… - Royal Society …, 2019 - royalsocietypublishing.org
Modern trends in the greener synthesis and fabrication of inorganic, organic and
coordination compounds, materials, nanomaterials, hybrids and nanocomposites are …

Sulfones as Chemical Chameleons: Versatile Synthetic Equivalents of Small‐Molecule Synthons

BM Trost, CA Kalnmals - Chemistry–A European Journal, 2019 - Wiley Online Library
Sulfones are flexible functional groups that can act as nucleophiles, electrophiles, or even
radicals. Changing the reaction conditions can completely alter the reactivity of a sulfonyl …

[HTML][HTML] Recent developments on ultrasound assisted catalyst-free organic synthesis

B Banerjee - Ultrasonics sonochemistry, 2017 - Elsevier
Mother Nature needs to be protected from ever increasing chemical pollutions associated
with synthetic organic processes. The fundamental challenge for today's methodologists is to …

Solvent‐free and catalysts‐free chemistry: a benign pathway to sustainability

MB Gawande, VDB Bonifacio, R Luque… - …, 2014 - Wiley Online Library
In the past decade, alternative benign organic methodologies have become an imperative
part of organic syntheses and chemical reactions. The various new and innovative …

Rongalite as C1 synthon in the synthesis of divergent pyridines and quinolines

H Gao, L Zhou, JP Wan, Y Liu - The Journal of Organic Chemistry, 2023 - ACS Publications
Rongalite has been used as a cheap and efficient carbon synthon for the synthesis of
divergent N-heteroaromatics, including different pyridines and quinolines. The selective …

Site-selective C–H functionalization–sulfination sequence to access aryl sulfonamides

EM Alvarez, MB Plutschack, F Berger, T Ritter - Organic Letters, 2020 - ACS Publications
Aryl sulfinates are precursors to a diverse number of sulfonyl-derived arenes, which are
common motifs in pharmaceuticals and agrochemicals. Here, we report a site-selective two …

Asymmetric sulfonylation with sulfur dioxide surrogates: a new access to enantiomerically enriched sulfones

J Zhang, P Wang, Y Li, J Wu - Chemical Communications, 2023 - pubs.rsc.org
Enantiomerically enriched sulfones occupy a prominent position in pharmaceutical
chemistry and synthetic chemistry. Compared with conventional methods, a direct …

Rongalite as C1 synthon and sulfone source: A practical sulfonylmethylation based on the separate-embedding strategy

XL Chen, CY Wu, JT Ma, SY Zhuang, ZC Yu… - Organic …, 2021 - ACS Publications
Rongalite has been used in several challenging synthetic transformations with operationally
simple and effective protocols. However, the employment of multiple characteristics of …

Reductive N-Formylation of Nitroarenes Mediated by Rongalite

HY Wang, XL Chen, CY Wu, DS Yang, T Chen… - Organic …, 2023 - ACS Publications
Herein, we disclose a straightforward approach to access transition-metal-free reductive N-
formylation of nitroarenes. This reaction integrates the dual role of rongalite, which acts as a …