Transition‐metal‐catalyzed C− H functionalization reactions with Cp* MIII catalysts (M= Co,
Rh, Ir) have found a wide variety of applications in organic synthesis. Albeit the intrinsic …

A critically important process in catalysis is the formation of an active catalyst from the
combination of a metal precursor and a ligand, as the efficacy of this reaction governs the …

Among sulfoximine derivatives containing a chiral sulfur center, benzothiadiazine‐1‐oxides
are important for applications in medicinal chemistry. Here, we report that the combination of …

Enantioselective C–H functionalization is a powerful tool for synthesizing chiral molecules.
In the past few years, the combination of high-valent group 9 metals with achiral Cpx ligands …

Recent advances in CpxMIII catalysis (M= Co, Rh, Ir) have enabled a variety of
enantioselective C (sp2)− H functionalization reactions, but enantioselective C (sp3)− H …

Computational methods based on quantum mechanical modeling are increasingly used to
provide insight into mechanistic aspects of homogeneous catalysis. While the potential and …

Amination of carboranes has a good application prospect in organic and pharmaceutical
synthesis. However, the current methods used for this transformation suffer from limitations …

Abstract The nondirected C (sp2)− H activation of simple arenes has advanced significantly
in recent years through the discovery of new catalyst systems that are able to perform …

The late-stage functionalization (LSF) of pharmaceutical and agrochemical compounds by
the site-selective activation of C–H bonds provides access to diverse structural analogs and …

An electrostatically directed meta borylation of sterically biased and unbiased substrates is
described. The borylation follows an electrostatic interaction between the partially positive …