Olefin metathesis in organic chemistry

M Schuster, S Blechert - Angewandte Chemie International …, 1997 - Wiley Online Library
Transition metal catalyzed C C bond formations belong to the most important reactions in
organic synthesis. One particularly interesting reaction is olefin metathesis, a metal …

Rhenium (VII) oxo and imido complexes: synthesis, structures, and applications

CC Romão, FE Kühn, WA Herrmann - Chemical reviews, 1997 - ACS Publications
The first examples of organometallic derivatives of metal oxides appeared in a syncretic
fashion and were merely regarded as laboratory curiosities in a time where low oxidation …

Transition metal catalysis in the Baeyer–Villiger oxidation of ketones

G Strukul - Angewandte Chemie International Edition, 1998 - Wiley Online Library
Environmentally friendly oxidizing agents such as hydrogen peroxide or dioxygen can be
used today in catalytic versions of the almost one century old Baeyer–Villiger oxidation with …

Organorhenium oxides

WA Herrmann, FE Kühn - Accounts of chemical research, 1997 - ACS Publications
Less than 20 years ago the entire class of organorhenium oxides was completely unknown,
but today an amazing wealth of these complexes exists. In the last decade many new facts …

Die Olefinmetathese in der organischen Synthese

M Schuster, S Blechert - Angewandte Chemie, 1997 - Wiley Online Library
Abstract Übergangsmetallkatalysierte C‐C‐Verknüpfungen gehören zu den wichtigsten
Reaktionen in der organischen Synthese. Eine interessante Reaktion aus dieser Klasse ist …

Progress toward the first observation of parity violation in chiral molecules by high‐resolution laser spectroscopy

B Darquié, C Stoeffler, A Shelkovnikov, C Daussy… - Chirality, 2010 - Wiley Online Library
Parity violation (PV) effects in chiral molecules have so far never been experimentally
observed. To take up this challenge, a consortium of physicists, chemists, theoreticians, and …

Recent advancements in ring closing olefin metathesis

A Fürstner - Topics in Catalysis, 1997 - Springer
A short overview on recent developments in ring closing metathesis (RCM) of 1, ω-dienes to
cycloalkenes is provided, with particular emphasis on applications to natural product …

Nucleophilic cyclocarbenes as ligands in metal halides and metal oxides

WA Herrmann, K Öfele, M Elison, FE Kühn… - Journal of …, 1994 - Elsevier
Abstract The nucleophilic cyclocarbene 1, 3-dimethylimidazolin-2-ylidene (1) reveals
universal ligand properties in metal coordination chemistry: in addition to the well-known …

Alkylrhenium oxides as homogeneous epoxidation catalysts: activity, selectivity, stability, deactivation

WA Herrmann, RW Fischer, MU Rauch… - Journal of molecular …, 1994 - Elsevier
Abstract Methyltrioxorhenium (VII)(MTO, 1a) and several congeners 1b and 2a-d of formula
R ReO 3 and R ReO 3· L, respectively, qualify as olefin epoxidation catalysts of high …

Methyltrioxorhenium and its applications in olefin oxidation, metathesis and aldehyde olefination

FE Kühn, A Scherbaum, WA Herrmann - Journal of organometallic …, 2004 - Elsevier
Organorhenium (VII) oxides, most notably methyltrioxorhenium (MTO) and several of its
derivatives gained significant importance as extremely versatile catalysts for olefin oxidation …