The golden age of thermally activated delayed fluorescence materials: design and exploitation

JM Dos Santos, D Hall, B Basumatary… - Chemical …, 2024 - ACS Publications
Since the seminal report by Adachi and co-workers in 2012, there has been a veritable
explosion of interest in the design of thermally activated delayed fluorescence (TADF) …

Solid state solvation: a fresh view

B Bardi, D Giavazzi, E Ferrari, A Iagatti… - Materials …, 2023 - pubs.rsc.org
The design of efficient organic electronic devices, including OLEDs, OPVs, luminescent
solar concentrators, etc., relies on the optimization of relevant materials, often constituted by …

Chiroptical properties of cyanine aggregates: hierarchical modelling from monomers to bundles

F Bertocchi, S Nizar, C Sissa, M Li, TW Ebbesen… - Chemical …, 2024 - pubs.rsc.org
Some achiral cyanine dyes form well-ordered chiral assemblies exhibiting pronounced
Circular Dichroism (CD) and Circularly Polarized Luminescence (CPL). Notably, achiral …

A Comprehensive Approach to Exciton Delocalization and Energy Transfer

D Giavazzi, S Saseendran, F Di Maiolo… - Journal of Chemical …, 2022 - ACS Publications
Electrostatic intermolecular interactions lie at the heart of both the Förster model for
resonance energy transfer (RET) and the exciton model for energy delocalization. In the …

From the Fermi Golden Rule to Open Quantum Systems: Basic Concepts on Non-radiative Rates

A Landi, DKA Phan Huu, A Painelli - The Journal of Physical …, 2024 - ACS Publications
The accurate estimate of nonradiative rates is a compelling endeavor to reliably address the
fate of excited states in molecular functional materials, an issue of fundamental relevance …

Fluorescence in quantum dynamics: Accurate spectra require post-mean-field approaches

CM Bustamante, ED Gadea, TN Todorov… - The Journal of …, 2023 - pubs.aip.org
Real time modeling of fluorescence with vibronic resolution entails the representation of the
light–matter interaction coupled to a quantum-mechanical description of the phonons and is …

Interplay between classical and quantum dissipation in light–matter dynamics

F Tarasi, TN Todorov, CM Bustamante… - The Journal of …, 2024 - pubs.aip.org
A quantum-electrodynamics approach is presented to describe the dynamics of electrons
that exchange energy with both photon and phonon baths. Our ansatz is a dissipative …