The biologically relevant coordination chemistry of iron and nitric oxide: electronic structure and reactivity
Nitric oxide (NO) is an important signaling molecule that is involved in a wide range of
physiological and pathological events in biology. Metal coordination chemistry, especially …
physiological and pathological events in biology. Metal coordination chemistry, especially …
Reduction of NO by diiron complexes in relation to flavodiiron nitric oxide reductases
Reduction of nitric oxide (NO) to nitrous oxide (N2O) is associated with immense biological
and health implications. Flavodiiron nitric oxide reductases (FNORs) are diiron containing …
and health implications. Flavodiiron nitric oxide reductases (FNORs) are diiron containing …
Distortion of the [FeNO]2 Core in Flavodiiron Nitric Oxide Reductase Models Inhibits N–N Bond Formation and Promotes Formation of Unusual Dinitrosyl Iron …
CJ White, MO Lengel, AJ Bracken… - Journal of the …, 2022 - ACS Publications
Flavodiiron nitric oxide reductases (FNORs) carry out the reduction of nitric oxide (NO) to
nitrous oxide (N2O), allowing infectious pathogens to mitigate toxic levels of NO generated …
nitrous oxide (N2O), allowing infectious pathogens to mitigate toxic levels of NO generated …
What Is the Right Level of Activation of a High-Spin {FeNO}7 Complex to Enable Direct N–N Coupling? Mechanistic Insight into Flavodiiron NO Reductases
Flavodiiron nitric oxide reductases (FNORs), found in pathogenic bacteria, are capable of
reducing nitric oxide (NO) to nitrous oxide (N2O) to detoxify NO released by the human …
reducing nitric oxide (NO) to nitrous oxide (N2O) to detoxify NO released by the human …
Direct NO reduction by a biomimetic iron (II) pyrazolate MOF
A novel metal‐organic framework (MOF) containing one‐dimensional, Fe2+ chains bridged
by dipyrazolate linkers and N, N‐dimethylformamide (DMF) ligands has been synthesized …
by dipyrazolate linkers and N, N‐dimethylformamide (DMF) ligands has been synthesized …
Reduction of Nitric Oxide to Nitrous Oxide in Flavodiiron Proteins: Catalytic Mechanism and Plausible Intermediates
MRA Blomberg, P Ädelroth - ACS Catalysis, 2023 - ACS Publications
The flavin dependent nonheme diiron proteins comprise a family of enzymes, which can act
as scavengers for both molecular oxygen and nitric oxide. The reduction of nitric oxide to …
as scavengers for both molecular oxygen and nitric oxide. The reduction of nitric oxide to …
Photoinduced NO and HNO Production from Mononuclear {FeNO}6 Complex Bearing a Pendant Thiol
CK Chiang, KT Chu, CC Lin, SR Xie… - Journal of the …, 2020 - ACS Publications
Light triggers the formation of HNO from a metal–nitrosyl species, facilitated by an
intramolecular pendant thiol proton. Two {FeNO} 6 complexes (the Enemark–Felthan …
intramolecular pendant thiol proton. Two {FeNO} 6 complexes (the Enemark–Felthan …
Bacterial nitric oxide reductase (NorBC) models employing click chemistry
Abstract Bacterial NO Reductase (NorBC or cNOR) is a membrane-bound enzyme found in
denitrifying bacteria that catalyzes the two-electron reduction of NO to N 2 O and water. The …
denitrifying bacteria that catalyzes the two-electron reduction of NO to N 2 O and water. The …
Nitric Oxide Oxygenation Reactions of Cobalt-Peroxo and Cobalt-Nitrosyl Complexes
Here, we report a comparative study of nitric oxide oxidation (NOO) reactions of CoIII-peroxo
(CoIII–O22–) and Co-nitrosyl ({CoNO} 8) complexes bearing the same N4-donor ligand …
(CoIII–O22–) and Co-nitrosyl ({CoNO} 8) complexes bearing the same N4-donor ligand …
Functional models for the mono-and dinitrosyl intermediates of FNORs: semireduction versus superreduction of NO
The reduction of NO to N2O by flavodiiron nitric oxide reductases (FNORs) is related to the
disruption of the defense mechanism in mammals against invading pathogens. The …
disruption of the defense mechanism in mammals against invading pathogens. The …