Photoactive ruthenium nitrosyls: Effects of light and potential application as NO donors
MJ Rose, PK Mascharak - Coordination chemistry reviews, 2008 - Elsevier
In recent years, various exogenous nitric oxide (NO) donors have been synthesized to
modulate NO concentrations in cellular environments and control physiological processes …
modulate NO concentrations in cellular environments and control physiological processes …
New features in the redox coordination chemistry of metal nitrosyls {M–NO+; M–NO; M–NO−(HNO)}
We describe new developments in the coordination chemistry of bound nitrosyl, considering
its three formal redox states: NO+, NO and NO−/HNO. We emphasize on the correlation …
its three formal redox states: NO+, NO and NO−/HNO. We emphasize on the correlation …
Ruthenium polypyridyl phototriggers: from beginnings to perspectives
L Zayat, O Filevich, LM Baraldo… - … Transactions of the …, 2013 - royalsocietypublishing.org
Octahedral Ru (II) polypyridyl complexes constitute a superb platform to devise photoactive
triggers capable of delivering entire molecules in a reliable, fast, efficient and clean way …
triggers capable of delivering entire molecules in a reliable, fast, efficient and clean way …
Catalysis of mononuclear aquaruthenium complexes in oxygen evolution from water: A new radical coupling path using hydroxocerium (IV) species
The mechanism of O2 evolution from water catalyzed by a series of mononuclear
aquaruthenium complexes,[Ru (terpy)(bpy)(OH2)] 2+,[Ru (tmtacn)(R2bpy)(OH2)] 2+(R= H …
aquaruthenium complexes,[Ru (terpy)(bpy)(OH2)] 2+,[Ru (tmtacn)(R2bpy)(OH2)] 2+(R= H …
Near-IR light-induced photorelease of nitric oxide (NO) on ruthenium nitrosyl complexes: formation, reactivity, and biological effects
Polypyridyl backbone nitrosyl complexes of ruthenium with the molecular framework [RuII
(antpy)(bpy) NO+/˙] n+ [4](PF6) 3 (n= 3),[4](PF6) 2 (n= 2), where antpy= 4′-(anthracene-9 …
(antpy)(bpy) NO+/˙] n+ [4](PF6) 3 (n= 3),[4](PF6) 2 (n= 2), where antpy= 4′-(anthracene-9 …
Photosensitization of Ruthenium nitrosyls to red light with an isoelectronic series of heavy-atom chromophores: experimental and density functional theory studies on …
MJ Rose, PK Mascharak - Inorganic chemistry, 2009 - ACS Publications
Three ruthenium nitrosyl-dye conjugates, namely,[((OMe) 2bQb) Ru (NO)(Resf)](RuNO-
Resf),[((OMe) 2bQb) Ru (NO)(Thnl)](RuNO-Thnl), and [((OMe) 2bQb) Ru (NO)(Seln)](RuNO …
Resf),[((OMe) 2bQb) Ru (NO)(Thnl)](RuNO-Thnl), and [((OMe) 2bQb) Ru (NO)(Seln)](RuNO …
Synthesis, spectroscopic analysis and photolabilization of water-soluble ruthenium (III)–nitrosyl complexes
AC Merkle, AB McQuarters, N Lehnert - Dalton Transactions, 2012 - pubs.rsc.org
In this paper, the synthesis, structural and spectroscopic characterization of a series of new
Ru (III)–nitrosyls of {RuNO} 6 type with the coligand TPA (tris (2-pyridylmethyl) amine) are …
Ru (III)–nitrosyls of {RuNO} 6 type with the coligand TPA (tris (2-pyridylmethyl) amine) are …
Electronic structure alternatives in nitrosylruthenium complexes
GK Lahiri, W Kaim - Dalton Transactions, 2010 - pubs.rsc.org
Coordination compounds [Ru (NO) Ln] containing an electro-active metal and potentially
non-innocent ligands NO (and L) can have ground state electronic structures formulated as …
non-innocent ligands NO (and L) can have ground state electronic structures formulated as …
Formation, reactivity, photorelease, and scavenging of NO in ruthenium nitrosyl complexes
The two newly designed nitrosyl complexes with Enemark–Feltham notation {RuNO} 6 and
{RuNO} 7 configurations have been isolated as the perchlorate salts in the molecular …
{RuNO} 7 configurations have been isolated as the perchlorate salts in the molecular …
Redox Properties of Ruthenium Nitrosyl Porphyrin Complexes with Different Axial Ligation: Structural, Spectroelectrochemical (IR, UV− Visible, and EPR), and …
Experimental and computational results for different ruthenium nitrosyl porphyrin complexes
[(Por) Ru (NO)(X)] n+(where Por2−= tetraphenylporphyrin dianion (TPP2−) or …
[(Por) Ru (NO)(X)] n+(where Por2−= tetraphenylporphyrin dianion (TPP2−) or …